Conspectus Alkene ozonolysis is a primary oxidation pathway for anthropogenic and
biogenic alkenes emitted into the troposphere. It is also an important source of atmospheric …

Criegee intermediates are very reactive carbonyl oxides that are formed in reactions of
unsaturated hydrocarbons with ozone (ozonolysis). Recently, Criegee intermediates have …

This article, the seventh in the series, presents kinetic and photochemical data sheets
evaluated by the IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation. It …

The reaction of ozone with isoprene, one of the most abundant volatile organic compounds
in the atmosphere, produces three distinct carbonyl oxide species (RR′ COO) known as …

Since the earliest explorations of quantum mechanics, it has been a topic of great interest
that quantum tunneling allows particles to penetrate classically insurmountable barriers …

Criegee intermediates are reactive species formed in the ozonolysis of alkenes. Their
subsequent chemistry is critical to an accounting of OH production, aerosol formation, and …

Ozonolysis of isoprene, the most abundant alkene, produces three distinct Criegee
intermediates (CIs): CH2OO, methyl vinyl ketone oxide (MVKO) and methacrolein oxide …

The kinetics of the simplest Criegee intermediate (CH2OO) reaction with water vapor was
revisited. By improving the signal-to-noise ratio and the precision of water concentration, we …

Criegee intermediates are important oxidants produced in the ozonolysis of alkenes in the
atmosphere. Quantitative kinetics of the reactions of Criegee intermediates are required for …

We introduce an approach for calculating perturbative corrections to the ring-polymer
instanton approximation to tunneling splittings (RPI+ PC) by computing higher-order terms in …