Recent advances in subphthalocyanines and related subporphyrinoids

G Lavarda, J Labella, MV Martínez-Díaz… - Chemical Society …, 2022 - pubs.rsc.org
Half a century after the synthesis of the first subporphyrinoid, the study of tripyrrole and
trisoindole porphyrin analogues constitutes a fervent and rapidly expanding research area …

Subphthalocyanines: contracted porphyrinoids with expanded applications

J Labella, T Torres - Trends in Chemistry, 2023 - cell.com
Subphthalocyanines (SubPcs) have undergone extensive research activity because of their
unique properties, rich chemistry, and tremendous applicability. Over decades, researchers …

Boron subphthalocyanine axial groups: a comprehensive set for studying the tuning of photophysical and electrochemical properties

R Zigelstein, TP Bender - Molecular Systems Design & Engineering, 2024 - pubs.rsc.org
Eighteen boron subphthalocyanines (BsubPcs) axial derivatives were synthesized through
axial exchange reactions with Br-BsubPc under relatively mild conditions to systematically …

Fluorinated boron subphthalocyanines: Lewis acid based templating chemistry facilitates random halide exchange, and fluoride versus chloride affects the basic …

E Bukuroshi, J Vestfrid, Z Gross… - New Journal of Chemistry, 2019 - pubs.rsc.org
A sub-group of the phthalocyanine family, the boron subphthalocyanines (BsubPcs), have
robust chemistry and can be readily modified at the axial and peripheral positions to tune …

Controlling the optical properties of boron subphthalocyanines and their analogues

M Dowds, MB Nielsen - Molecular Systems Design & Engineering, 2021 - pubs.rsc.org
Boron subphthalocyanines (SubPcs) are cone shaped π-conjugated molecules comprised
of three azomethine-bridged isoindole units and a central boron atom with an axial …

Lewis-acid-catalyzed BODIPY boron functionalization using trimethylsilyl nucleophiles

G Zhang, M Wang, FR Fronczek, KM Smith… - Inorganic …, 2018 - ACS Publications
A novel and straightforward strategy for boron functionalization in boron dipyrromethenes
(BODIPYs) is developed. In particular, this synthetic strategy provides new possibilities for …

“Homoleptic” Tetracoordinate Boron Compounds

X Li, Q Song - Inorganic Chemistry, 2024 - ACS Publications
“Homoleptic” tetracoordinate boron compounds, in which the central boron atom links to four
identical atoms, are a special and important family of boron compounds. During the past …

Optical resolution via chiral auxiliaries of curved subphthalocyanine aromatics

G Lavarda, L Tejerina, T Torres, MV Martínez-Díaz - Chemical Science, 2024 - pubs.rsc.org
Chiral conjugated materials with curved topologies hold significant promise for advanced
optoelectronic applications. Among these, bowl-shaped subphthalocyanine (SubPc) …

Thieno‐fused subporphyrazines: a new class of light harvesters

H Gotfredsen, FE Storm, AV Muñoz… - … A European Journal, 2017 - Wiley Online Library
Boron subphthalocyanines comprised of three isoindole units bridged by aza‐linkages are
attractive light harvesters on account of their intense low‐energy absorptions. Herein, we …

Electrophilic and nucleophilic displacement reactions at the bridgehead borons of tris (pyridyl) borate scorpionate complexes

J Goura, J McQuade, D Shimoyama… - Chemical …, 2022 - pubs.rsc.org
Although a wide variety of boron-based “scorpionate” ligands have been implemented, a
modular route that offers facile access to different substitution patterns at boron has yet to be …