Large-sized coordination clusters have emerged as a new class of molecular materials in
which many metal atoms and organic ligands are integrated to synergize their properties. As …

Abstract Embedding cubane [M4 (OH) 4](M= Ni, Co) clusters within the matrix of metal–
organic frameworks (MOFs) is a strategy to develop materials with unprecedented …

One of the most intriguing nitrogen based aromatic heterocycles is 1, 2, 4, 5-tetrazine or s-
tetrazine (TTZ) thanks to its electron acceptor character and fluorescence properties and the …

The first examples of metallacycles containing rare earth ions bridged by radicals are
reported. The molecular triangles [Ln3 (hfac) 6 (bptz•–) 3](Ln= DyIII, YIII; hfac= 1, 1, 1, 5, 5, 5 …

Condensation of an inherently C3‐symmetric polychlorotriphenylmethyl (PTM) radical
trisaldehyde with tris (2‐aminoethyl) amine (TREN) yields a [4+ 4] tetrahedral radical cage …

Precise control of the structures and magnetic properties of a molecular material constitutes
an important challenge to realize tailor-made magnetic function. Herein, we report that the …

Four hexanuclear circular helicates,{[Dy6L6 (DMF) 12]· 6CF3SO3· 12DMF} 2 (1Dy),{[Gd6L6
(DMF) 12]· 6CF3SO3· 12DMF} 2 (1Gd),[Dy6L6 (DMF) 10 (H2O) 2]· 6ClO4· 4H2O· 10DMF …

Organic diradicals are uncommon species that have been intensely studied for their unique
properties and potential applicability in a diverse range of innovative fields. While there is a …

Abstract The reaction of 5-fluorine-3-(3, 5-dicarboxylphenxoy) benzoic acid (H 3 L) with
cobalt (II) salt in presence of 1, 1'-(1, 4-butanediyl) bis (imidazole)(bib) linker yielded two …

The unique electronic nature of the 1, 2, 4, 5-tetrazine or s-tetrazine (tz) ring has sparked
tremendous scientific interest over the last few years. Tetrazines have found numerous …