Sm (II)-mediated proton-coupled electron transfer: quantifying very weak N–H and O–H homolytic bond strengths and factors controlling them
EA Boyd, JC Peters - Journal of the American Chemical Society, 2022 - ACS Publications
Coordination of alcohols to the single-electron reductant samarium diiodide (SmI2) results in
substantial O–H bond weakening, affording potent proton-coupled electron transfer (PCET) …
substantial O–H bond weakening, affording potent proton-coupled electron transfer (PCET) …
Highly Selective Fe-Catalyzed Nitrogen Fixation to Hydrazine Enabled by Sm(II) Reagents with Tailored Redox Potential and pKa
EA Boyd, JC Peters - Journal of the American Chemical Society, 2023 - ACS Publications
Controlling product selectivity in multiproton, multielectron reductions of unsaturated small
molecules is of fundamental interest in catalysis. For the N2 reduction reaction (N2RR) in …
molecules is of fundamental interest in catalysis. For the N2 reduction reaction (N2RR) in …
Uranium (III) Redox Chemistry Assisted by a Hemilabile Bis (phenolate) Cyclam Ligand: Uranium–Nitrogen Multiple Bond Formation Comprising a trans-{RN U (VI) …
A new monoiodide U (III) complex anchored on a hexadentate dianionic 1, 4, 8, 11-
tetraazacyclotetradecane-based bis (phenolate) ligand,[U (κ6-{(tBu2ArO) 2Me2-cyclam}) …
tetraazacyclotetradecane-based bis (phenolate) ligand,[U (κ6-{(tBu2ArO) 2Me2-cyclam}) …
Complexation of Ln3+ Ions with Cyclam Dipicolinates: A Small Bridge that Makes Huge Differences in Structure, Equilibrium, and Kinetic Properties
A Rodriguez-Rodriguez, M Regueiro-Figueroa… - Inorganic …, 2016 - ACS Publications
The coordination properties toward the lanthanide ions of two macrocyclic ligands based on
a cyclam platform containing picolinate pendant arms have been investigated. The synthesis …
a cyclam platform containing picolinate pendant arms have been investigated. The synthesis …
Unusual variability of isomers in copper (II) complexes with 1, 8-bis (2-hydroxybenzyl)-cyclam
M Maďar, J Faltejsek, H Bušková, L Koláčná… - Dalton …, 2025 - pubs.rsc.org
Copper isotopes and their complexes are intensively studied due to their high potential for
applications in radiodiagnosis and radiotherapy. Here, we study the CuII complex of 1, 8-bis …
applications in radiodiagnosis and radiotherapy. Here, we study the CuII complex of 1, 8-bis …
Synthesis, Characterization, and Reactivity Studies of New Cyclam-Based Y (III) Complexes
[(Bn2Cyclam) Y (N (SiMe3) 2)] was prepared by reaction of H2Bn2Cyclam with Y [N (SiMe3)
2] 3. The protonation of the macrocycle ligand in [(Bn2Cyclam) Y (N (SiMe3) 2)] is observed …
2] 3. The protonation of the macrocycle ligand in [(Bn2Cyclam) Y (N (SiMe3) 2)] is observed …
A novel samarium (II) complex bearing a dianionic bis (phenolate) cyclam ligand: synthesis, structure and electron-transfer reactions
L Maria, M Soares, IC Santos, VR Sousa, E Mora… - Dalton …, 2016 - pubs.rsc.org
The reaction of the hexadentate dianionic 1, 4, 8, 11-tetraazacyclotetradecane-based bis
(phenolate) ligand,(tBu2ArO) 2Me2-cyclam2−, with [SmI2 (thf) 2] in thf resulted in the …
(phenolate) ligand,(tBu2ArO) 2Me2-cyclam2−, with [SmI2 (thf) 2] in thf resulted in the …
Toward the understanding of radical reactions: Experimental and computational studies of titanium (III) diamine bis (phenolate) complexes
S Barroso, F Madeira, MJ Calhorda… - Inorganic …, 2013 - ACS Publications
Radical reactions of titanium (III)[Ti (t Bu2O2NN′) Cl (S)](S= THF, 1; S= py, 2; t
Bu2O2NN′= Me2N (CH2) 2N (CH2-2-O-3, 5-t Bu2C6H2) 2) are described. Reactions with …
Bu2O2NN′= Me2N (CH2) 2N (CH2-2-O-3, 5-t Bu2C6H2) 2) are described. Reactions with …
Cooperative effects of metal cations and coordination modes on luminescent s-block metal–organic complexes constructed from V-shaped 4, 4′-sulfonyldiphenol
C Li, ZP Deng, LH Huo, S Gao - CrystEngComm, 2018 - pubs.rsc.org
The self-assembly of 4, 4′-sulfonyldiphenol (H2sdp) with s-block metal salts in an aqueous
or mixed H2O/alcohol solution gives rise to the formation of 13 new complexes, namely,[Li …
or mixed H2O/alcohol solution gives rise to the formation of 13 new complexes, namely,[Li …
New zirconium complexes supported by N-heterocyclic carbene (NHC) ligands: Synthesis and assessment of hydroamination catalytic properties
S Barroso, SRMM De Aguiar, RF Munhá… - Journal of Organometallic …, 2014 - Elsevier
Abstract Reactions of 2-(bromomethyl)-4, 6-di-tert-butylphenol or 2-(bromomethyl)-4, 6-bis (2-
phenylpropan-2-yl) phenol with 1H-imidazole led to syntheses of N, N-disubstituted …
phenylpropan-2-yl) phenol with 1H-imidazole led to syntheses of N, N-disubstituted …