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Electrochemistry of metal-metal bonded diruthenium complexes
This review summarizes the known electrochemistry of metal-metal bonded diruthenium
complexes containing an air-stable Ru 2 4+, Ru 2 5+ or Ru 2 6+ core or an in-situ generated …
complexes containing an air-stable Ru 2 4+, Ru 2 5+ or Ru 2 6+ core or an in-situ generated …
N-Heterocyclic carbene–carbodiimide (NHC–CDI) betaine adducts: synthesis, characterization, properties, and applications
N-Heterocyclic carbenes (NHCs) are an important class of reactive organic molecules used
as ligands, organocatalysts, and σ-donors in a variety of electroneutral ylide or betaine …
as ligands, organocatalysts, and σ-donors in a variety of electroneutral ylide or betaine …
A diruthenium metallodrug as a potent inhibitor of amyloid-β aggregation: synergism of mechanisms of action
The physical and chemical properties of paddlewheel diruthenium compounds are highly
dependent on the nature of the ligands surrounding the bimetallic core. Herein, we compare …
dependent on the nature of the ligands surrounding the bimetallic core. Herein, we compare …
Effect of equatorial ligand substitution on the reactivity with proteins of paddlewheel diruthenium complexes: Structural studies
The paddlewheel [Ru2Cl (O2CCH3) 4] complex was previously reported to react with the
model protein hen egg white lysozyme (HEWL), forming adducts with two diruthenium …
model protein hen egg white lysozyme (HEWL), forming adducts with two diruthenium …
Torsion Effects Beyond the δ Bond and the Role of π Metal‐Ligand Interactions
Previous studies on bimetallic paddlewheel compounds have established a direct
correlation between metal–metal distance and ligand torsion angles, leading to the rule that …
correlation between metal–metal distance and ligand torsion angles, leading to the rule that …
Diruthenium complexes as pH-responsive delivery systems: a quantitative assessment
I Coloma, M Cortijo, MJ Mancheño… - Inorganic Chemistry …, 2023 - pubs.rsc.org
The controlled release of biologically active species from diruthenium compounds is crucial
for the development of selective drug delivery systems based on such complexes, which in …
for the development of selective drug delivery systems based on such complexes, which in …
Charge effect in protein metalation reactions by diruthenium complexes
The properties of paddlewheel diruthenium compounds significantly depend on the nature
of the bridging equatorial ligands. The charge of these complexes is a factor to take into …
of the bridging equatorial ligands. The charge of these complexes is a factor to take into …
New insights into progressive ligand replacement from [Ru 2 Cl (O 2 CCH 3) 4]: synthetic strategies and variation in redox potentials and paramagnetic shifts
The complete series of [Ru2Cl (Dp-FPhF) x (O2CCH3) 4− x](x= 1–4; Dp-FPhF−= N, N′-bis
(4-fluorophenyl) formamidinate) compounds, has been prepared and characterized by a …
(4-fluorophenyl) formamidinate) compounds, has been prepared and characterized by a …
Exchange of equatorial ligands in protein-bound paddlewheel Ru 2 5+ complexes: new insights from X-ray crystallography and quantum chemistry
Here we report the binding of the diruthenium complex [Ru2Cl (Dp-CNPhF)(O2CCH3) 3] n
(Dp-CNPhF−= N, N′-bis (4-cyanophenyl) formamidinate) to the model protein bovine …
(Dp-CNPhF−= N, N′-bis (4-cyanophenyl) formamidinate) to the model protein bovine …
[HTML][HTML] Ultrasound-assisted synthesis of water-soluble monosubstituted diruthenium compounds
The elusive monosubstituted diruthenium complexes [Ru 2 Cl (DAniF)(O 2 CMe) 3](1),[Ru 2
Cl (DPhF)(O 2 CMe) 3](2),[Ru 2 Cl (Dp-CNPhF)(O 2 CMe) 3](3),[Ru 2 Cl (Do-TolF)(O 2 CMe) …
Cl (DPhF)(O 2 CMe) 3](2),[Ru 2 Cl (Dp-CNPhF)(O 2 CMe) 3](3),[Ru 2 Cl (Do-TolF)(O 2 CMe) …