One-pot reactions elaborated around transition metal-catalyzed isomerization of alkenes not
only offer the inherent advantages of atom-, step-and redox-economy but also enable the …

Presented herein is a novel synthesis of indenone-fused pyran derivatives via the cascade
reactions of aryl enaminones with cyclopropenones. The formation of products involves a …

A protocol for the C–H activation/iodination of benzoic acids catalyzed by a simple iridium
complex has been developed. The method described in this paper allows the ortho-selective …

Mono and dichloro‐substituted organic molecules are shown to possess significant roles in
various fields, especially in medicinal chemistry. One approach to synthesizing these …

The allylic alcohol structural motif is prevalent in many important molecules and valuable
building blocks. The rearrangement reaction is one of the most important transformations …

An efficient visible-light-mediated ketyl–ynamide coupling by employing ynamides bearing
alkyl sulfonyl substituents to deliver eneindolin-3-ols has been developed. Subsequent 1, 3 …

The selective synthesis of α-functionalized ketones with two similar enolizable positions can
be accomplished using allylic alcohols and iridium (III) catalysts. A formal 1, 3-hydrogen shift …

The 1, 3-rearrangement of allylic derivatives has rarely been reported, except for allylic
alcohols. Herein, we describe an iridium-catalyzed 1, 3-rearrangement of readily available …

The isomerization of dienyl alcohols and polyenyl alkyl ethers catalyzed by TBD (1, 5, 7-
triazabicyclo [4.4. 0] dec-5-ene) under metal-free conditions is presented. Two reaction …

Remarkably simple IrIII catalysts enable the isomerization of primary and sec‐allylic alcohols
under very mild reaction conditions. X‐ray absorption spectroscopy (XAS) and mass …