Polynuclear NiII and MnII azido bridging complexes. Structural trends and magnetic behavior

J Ribas, A Escuer, M Monfort, R Vicente… - Coordination Chemistry …, 1999 - Elsevier
The azide anion is a good bridging ligand for divalent metal ions, mainly CuII, NiII and MnII.
It may give end-to-end (1, 3) or end-on (1, 1) coordination modes. As a general trend, the 1 …

The bridging azido ligand as a central “player” in high-nuclearity 3d-metal cluster chemistry

A Escuer, J Esteban, SP Perlepes… - Coordination Chemistry …, 2014 - Elsevier
The chemistry of the azido-bridged coordination clusters continues to attract the intense
interest of synthetic inorganic chemists and scientists working in the interdisciplinary field of …

Molecular ferromagnets

VI Ovcharenko, RZ Sagdeev - Russian chemical reviews, 1999 - pubs.rsc.org
Molecular ferromagnets Page 1 Abstract. The state-of-the-art, achievements, problems and
prospects of an actively develo** area of supramolecular chemistry, viz., the design of …

Asymmetric Azido− Copper (II) Bridges: Ferro-or Antiferromagnetic? Experimental and Theoretical Magneto− Structural Studies

S Triki, CJ Gómez-García, E Ruiz… - Inorganic …, 2005 - ACS Publications
Reaction of NaN3 with the [CuII (tn)] 2+ ion (tn= 1, 3-diaminopropane) in basic aqueous
solution yields the azido-bridged complex of formula [Cu2 (tn) 2 (N3) 4](1), which is …

Magnetic coupling in end-to-end azido-bridged copper and nickel binuclear complexes: A theoretical study

F Fabrizi De Biani, E Ruiz, J Cano, JJ Novoa… - Inorganic …, 2000 - ACS Publications
The influence of structural parameters on the exchange coupling J between metal atoms in
end-to-end azido-bridged binuclear complexes of Cu (II) and Ni (II) has been studied by …

Unusual Ferromagnetic Couplings in Single End‐to‐End Azide‐Bridged Cobalt(II) and Nickel(II) Chain Systems

CS Hong, J Koo, SK Son, YS Lee… - … –A European Journal, 2001 - Wiley Online Library
Two new one‐dimensional single azide‐bridged metal (ii) compounds [{M (5‐
methylpyrazole) 4 (N3)} n](ClO4) n (H2O) n [M= Co (1 a), Ni (2 a)] were prepared by treating …

Synthesis and Structural Characterization of [Mn(ethyl isonicotinate)2(N3)2]n, a Two-Dimensional Alternating Ferromagnetic−Antiferromagnetic Compound …

A Escuer, R Vicente, MAS Goher… - Inorganic …, 1996 - ACS Publications
Three compounds with formula [Mn (L) 2 (N3) 2] n, in which L is 4-acpy= 4-acetylpyridine (1),
Etinc= ethyl isonicotinate (2), and py= pyridine (3), have been studied from the magnetic …

Azide chemistry–an inorganic perspective, Part I metal azides: overview, general trends and recent developments

WP Fehlhammer, W Beck - Zeitschrift für anorganische und …, 2013 - Wiley Online Library
Abstract With Sharpless' and Meldal's discovery of the immensely supportive effect that
metal catalysis has on Huisgen's classical 1, 3‐dipolar cycloaddition, azides (RN3)–long …

A Metamagnetic Two‐Dimensional Molecular Material with Nickel(II) and Azide

M Monfort, I Resino, J Ribas… - Angewandte …, 2000 - Wiley Online Library
Verbrückende Azidoliganden übertragen sowohl ferro-als auch antiferromagnetische
Wechselwirkungen. Der im Kristall Schichten bildende Komplex [Ni (μ-N 3) 2 (N, N-Et 2-N …

Ground-state phase diagram and magnetization curves of the spin-1 antiferromagnetic Heisenberg chain with bond alternation and uniaxial single-ion-type anisotropy

T Tonegawa, T Nakao, M Kaburagi - … of the Physical Society of Japan, 1996 - journals.jps.jp
Ground-state properties of the spin-1 antiferromagnetic Heisenberg chain with bond
alternation and uniaxial single-ion-type anisotropy, which is described by the Hamiltonian …