Synthesis and applications of anisotropic nanoparticles with precisely defined dimensions
Shape and size play powerful roles in determining the properties of a material; controlling
these aspects with precision is therefore an important, fundamental goal of the chemical …
these aspects with precision is therefore an important, fundamental goal of the chemical …
Porphyrin-based supramolecular polymers
Porphyrin derivatives are ubiquitous in bio-organisms and are associated with proteins that
play important biological roles, such as oxygen transport, photosynthesis, and catalysis …
play important biological roles, such as oxygen transport, photosynthesis, and catalysis …
Mutual monomer orientation to bias the supramolecular polymerization of [6] helicenes and the resulting circularly polarized light and spin filtering properties
We report on the synthesis and self-assembly of 2, 15-and 4, 13-disubstituted carbo [6]
helicenes 1 and 2 bearing 3, 4, 5-tridodecyloxybenzamide groups. The self-assembly of …
helicenes 1 and 2 bearing 3, 4, 5-tridodecyloxybenzamide groups. The self-assembly of …
Multistep, site-selective noncovalent synthesis of two-dimensional block supramolecular polymers
N Sasaki, J Kikkawa, Y Ishii, T Uchihashi, H Imamura… - Nature Chemistry, 2023 - nature.com
Although the principles of noncovalent bonding are well understood and form the basis for
the syntheses of many intricate supramolecular structures, supramolecular noncovalent …
the syntheses of many intricate supramolecular structures, supramolecular noncovalent …
Controlled noncovalent synthesis of secondary supramolecular polymers
Dynamic supramolecular polymers, with their functional similarities to classical covalent
polymers and their adaptive and self-repairing nature reminiscent of biological assemblies …
polymers and their adaptive and self-repairing nature reminiscent of biological assemblies …
Pathway complexity in supramolecular copolymerization and blocky star copolymers by a hetero-seeding effect
This study unravels the intricate kinetic and thermodynamic pathways involved in the
supramolecular copolymerization of the two chiral dipolar naphthalene monoimide (NMI) …
supramolecular copolymerization of the two chiral dipolar naphthalene monoimide (NMI) …
Secondary nucleation-triggered physical cross-links and tunable stiffness in seeded supramolecular hydrogels
Mechanistic understanding and the control of molecular self-assembly at all hierarchical
levels remain grand challenges in supramolecular chemistry. Functional realization of …
levels remain grand challenges in supramolecular chemistry. Functional realization of …
Stereoselective primary and secondary nucleation events in multicomponent seeded supramolecular polymerization
Bioinspired, kinetically controlled seeded growth has been recently shown to provide length,
dispersity, and sequence control on the primary structure of dynamic supramolecular …
dispersity, and sequence control on the primary structure of dynamic supramolecular …
Polymorphism in Squaraine Dye Aggregates by Self‐Assembly Pathway Differentiation: Panchromatic Tubular Dye Nanorods versus J‐Aggregate Nanosheets
A bis (squaraine) dye equipped with alkyl and oligoethyleneglycol chains was synthesized
by connecting two dicyanomethylene substituted squaraine dyes with a phenylene spacer …
by connecting two dicyanomethylene substituted squaraine dyes with a phenylene spacer …
Tricomponent supramolecular multiblock copolymers with tunable composition via sequential seeded growth
Synthesis of supramolecular block co‐polymers (BCP) with small monomers and predictive
sequence requires elegant molecular design and synthetic strategies. Herein we report the …
sequence requires elegant molecular design and synthetic strategies. Herein we report the …