Three diaryliodonium tetrachloroaurates (III),[Ar1IAr2][AuCl4](Ar1/Ar2= Ph/Ph (1), Ph/Mes
(2), o-(C6H4) 2 (3)), were obtained as solids (62–80%) by the metathetical reaction of …

Hypervalent iodine (III)-derivatives display higher catalytic activity than other aliphatic and
aromatic iodine (I)–or bromine (I)-containing substrates for a Knorr-type reaction of N-acetyl …

Predominantly, carbon atoms of various species function as acceptors of noncovalent
interactions when they are part of a π-system. Here, we report on the discovery of a halogen …

Palladium (II) and platinum (II) complexes featuring metalla-N-heterocyclic carbenes (7–12)
were synthesised via metal-mediated coupling between equimolar cis-[MCl2 (CNR) 2](R= 2 …

Among the different noncovalent interactions, halogen bonds have captured wide attention
in the last years. Their stability has been rationalized in electrostatic terms by appealing to …

Phosphorescent PtII-based cyclometalated complexes co-crystallise with bromo-and
iodosubstituted perfluorinated arenes to give 1: 1 adducts. X-FArenes in these co-crystals …

Two isomorphous series including the adducts trans-[PdI2 (CNC6H4-4-X) 2]· 2I2 [(1–3)· 2I2;
X= Cl 1, Br 2, I 3] and the complexes cis-[PdCl2 (CNC6H4-4-X)(PPh3)](4–6; X= Cl 4, Br 5, I …

Luminescent cyclometalated complexes [M (C^ N^ N) CN](M= Pt, Pd; HC^ N^ N= pyridinyl‐
(M= Pt 1, Pd 5), benzyltriazolyl‐(M= Pt 2), indazolyl‐(M= Pt 3, Pd 6), pyrazolyl …

We provide a Cambridge Structural Database (CSD) analysis of the role of halogen bonds
and halogen··· halogen interactions in the solid-state structures of porphyrins. This survey …

A high-fidelity and self-complementary halogen bonding moiety, 2-iodooxazole, was
identified using density functional theory-based calculations. Installation of 2-iodooxazole on …