[HTML][HTML] Spin state switching in iron coordination compounds

P Gütlich, AB Gaspar, Y Garcia - Beilstein journal of organic …, 2013 - beilstein-journals.org
The article deals with coordination compounds of iron (II) that may exhibit thermally induced
spin transition, known as spin crossover, depending on the nature of the coordinating ligand …

Spin crossover complexes with N4O2 coordination sphere—The influence of covalent linkers on cooperative interactions

B Weber - Coordination Chemistry Reviews, 2009 - Elsevier
About 10 years ago Jäger and co-workers demonstrated the possibility of preparing an iron
(II) spin crossover complex of a Schiff-base like N2O2 coordinating ligand in combination …

Spin-crossover iron (II) coordination polymer with fluorescent properties: Correlation between emission properties and spin state

C Lochenie, K Schötz, F Panzer, H Kurz… - Journal of the …, 2018 - ACS Publications
A spin-crossover coordination polymer [Fe (L1)(bipy)] n (where L= a N2O22–coordinating
Schiff base-like ligand bearing a phenazine fluorophore and bipy= 4, 4′-bipyridine) was …

An iron (II) spin-crossover complex with a 70 K wide thermal hysteresis loop

B Weber, W Bauer, J Obel - Angewandte Chemie International …, 2008 - eref.uni-bayreuth.de
Going loopy: A new iron (II) spin-crossover complex displays a 70 K wide thermal hysteresis
loop, which can be explained by an intermolecular 2D network of hydrogen bonds. This is …

Large Thermal Hysteresis for Iron(II) Spin Crossover Complexes with N-(Pyrid-4-yl)isonicotinamide

C Lochenie, W Bauer, AP Railliet, S Schlamp… - Inorganic …, 2014 - ACS Publications
A new series of iron (II) 1D coordination polymers with the general formula [FeL1 (pina)]· x
solvent with L1 being a tetradentate N2O22–coordinating Schiff-base-like ligand [([3, 3′]-[1 …

Advances in polynuclear iron (II), iron (III) and cobalt (II) spin‐crossover compounds

KS Murray - European Journal of Inorganic Chemistry, 2008 - Wiley Online Library
This review describes the recent advances made in the syntheses, structures (including the
use of synchrotron sources and variable-temperature crystal structures and PXRD …

Evidence for surface effects on the intermolecular interactions in Fe (II) spin crossover coordination polymers

TK Ekanayaka, H Kurz, KA McElveen, G Hao… - Physical Chemistry …, 2022 - pubs.rsc.org
From X-ray absorption spectroscopy (XAS) and X-ray photoemission spectroscopy (XPS), it
is evident that the spin state transition behavior of Fe (II) spin crossover coordination …

Cooperative Spin Transition in the Two-Dimensional Coordination Polymer [Fe(4,4′-bipyridine)2(NCX)2]·4CHCl3 (X = S, Se)

CJ Adams, MC Muñoz, RE Waddington… - Inorganic …, 2011 - ACS Publications
Two new isostructural two-dimensional (2D) coordination polymers exhibiting spin crossover
(SCO) behavior of formulation [Fe (4, 4′-bipy) 2 (NCX) 2]· 4CHCl3 (4, 4′-bipy= 4, 4 …

Fe II spin crossover complexes containing N 4 O 2 donor ligands

B Dey, V Chandrasekhar - Dalton Transactions, 2022 - pubs.rsc.org
Spin crossover (SCO) is one of the most studied magnetic bistable phenomena because of
its application in the field of multifunctional magnetic materials. FeII complexes in a N6 …

Influence of hydrogen bonding on the hysteresis width in iron (II) spin‐crossover complexes

B Weber, W Bauer, T Pfaffeneder, MM Dîrtu, AD Naik… - 2011 - Wiley Online Library
A detailed investigation on the properties of the high‐temperature and low‐temperature
modifications of the iron (II) spin‐crossover complex [FeL1 (HIm) 2](1) and its isotopic …