A Highly Efficient Near‐Infrared‐Emissive Copolymer with a N= N Double‐Bond π‐Conjugated System Based on a Fused Azobenzene–Boron Complex
M Gon, K Tanaka, Y Chujo - Angewandte Chemie International …, 2018 - Wiley Online Library
Fused azobenzene–boron complexes (BAzs) show highly efficient near‐infrared (NIR)
emission from the nitrogen–nitrogen double bond (N= N) containing π‐conjugated …
emission from the nitrogen–nitrogen double bond (N= N) containing π‐conjugated …
catalytic azoarene synthesis from aryl azides enabled by a dinuclear Ni complex
Azoarenes are valuable chromophores that have been extensively incorporated as
photoswitchable elements in molecular machines and biologically active compounds. Here …
photoswitchable elements in molecular machines and biologically active compounds. Here …
Catalytic synthesis of conjugated azopolymers from aromatic diazides
Conjugated polymers containing main chain azoarene repeat units are synthesized by a
dinickel catalyzed N= N coupling reaction of aromatic diazides. The polymerization exhibits …
dinickel catalyzed N= N coupling reaction of aromatic diazides. The polymerization exhibits …
Facile Cu (I)-catalyzed oxidative coupling of anilines to azo compounds and hydrazines with diaziridinone under mild conditions
Y Zhu, Y Shi - Organic letters, 2013 - ACS Publications
A mild and highly efficient Cu (I)-catalyzed oxidative coupling of anilines is described.
Various primary and secondary anilines can be efficiently coupled under mild conditions to …
Various primary and secondary anilines can be efficiently coupled under mild conditions to …
Recent Advances in Catalytic Nitrogen–Nitrogen Bond Formation Reactions
JL Hu, Y Wu, Y Gao, Y Wang, P Wang - ACS Catalysis, 2024 - ACS Publications
The lack of effective strategies for direct construction of nitrogen–nitrogen bonds has
hampered developments in the synthesis and application of molecules containing hydrazine …
hampered developments in the synthesis and application of molecules containing hydrazine …
Continuous-flow oxidative homocouplings without auxiliary substances: Exploiting a solid base catalyst
The catalytic oxidative dimerization of aromatic amines and acetylenes is of outstanding
synthetic importance among homocoupling reactions. Both transformations necessitate the …
synthetic importance among homocoupling reactions. Both transformations necessitate the …
Oxidative coupling of anilines to azobenzenes using heterogeneous manganese oxide catalysts
M Wang, J Ma, M Yu, Z Zhang, F Wang - Catalysis Science & …, 2016 - pubs.rsc.org
We herein report the transition metal oxide-catalyzed synthesis of azobenzenes through the
oxidative coupling of anilines. An octahedral molecular sieve of manganese oxide, OMS-2 …
oxidative coupling of anilines. An octahedral molecular sieve of manganese oxide, OMS-2 …
Cu (I) catalyzed dehydrogenative homo coupling of aromatic amines under simple and mild reaction conditions
An efficient protocol for the synthesis of a variety of azobenzenes and hydrazines from
aromatic amines under mild reaction conditions is developed using Cu (I) catalyst. The …
aromatic amines under mild reaction conditions is developed using Cu (I) catalyst. The …
A straightforward protocol for the highly efficient preparation of main-chain azo polymers directly from bisnitroaromatic compounds by the photocatalytic process
A novel strategy for the synthesis of main-chain Azo polymers directly from bisnitroaromatic
compounds by the photocatalytic process has been achieved under mild conditions. This …
compounds by the photocatalytic process has been achieved under mild conditions. This …
Synthesis of monodisperse aromatic azo oligomers toward gaining new insight into the isomerization of π-conjugated azo systems
π-Conjugated aromatic azo main-chain polymers are commonly distinguished as promising
photosensitive materials. However their rigid-rod structure decreases their photoswitching …
photosensitive materials. However their rigid-rod structure decreases their photoswitching …