Metal-catalysed C–H bond activation and borylation

R Bisht, C Haldar, MMM Hassan, ME Hoque… - Chemical Society …, 2022 - pubs.rsc.org
Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …

Transition metal–catalyzed remote C─ H borylation: An emerging synthetic tool

MMM Hassan, S Guria, S Dey, J Das… - Science …, 2023 - science.org
Transition metal–catalyzed C─ H bond activation and borylation is a powerful synthetic
method that offers versatile synthetic transformation from organoboron compounds to …

Forging C− heteroatom bonds by transition-metal-catalyzed enantioselective C–H functionalization

Q Zhang, LS Wu, BF Shi - Chem, 2022 - cell.com
Direct C–H functionalization has recently emerged as one of the most efficient strategies to
access structurally complex molecules from readily accessible feedstocks in an atom-and …

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

Z Chen, B Wang, J Zhang, W Yu, Z Liu… - Organic Chemistry …, 2015 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Transition metal-catalyzed site-and regio-divergent C–H bond functionalization

L **, DS Chung, J Bouffard, S Lee - Chemical Society Reviews, 2017 - pubs.rsc.org
Recent advances in transition metal-catalyzed C–H bond functionalization have profoundly
impacted synthetic strategy. Since organic substrates typically contain several chemically …

Remarkably Efficient Iridium Catalysts for Directed C(sp2)–H and C(sp3)–H Borylation of Diverse Classes of Substrates

ME Hoque, MMM Hassan… - Journal of the American …, 2021 - ACS Publications
Here we describe the discovery of a new class of C–H borylation catalysts and their use for
regioselective C–H borylation of aromatic, heteroaromatic, and aliphatic systems. The new …

Recent advances in catalytic C− H borylation reactions

L Xu, G Wang, S Zhang, H Wang, L Wang, L Liu, J Jiao… - Tetrahedron, 2017 - Elsevier
In the past decades, the iridium-catalyzed C–H bond borylation and other newly discovered
catalytic borylation reactions have received extensive research interests and developed into …

Ion pair-directed regiocontrol in transition-metal catalysis: a meta-selective C–H borylation of aromatic quaternary ammonium salts

HJ Davis, MT Mihai, RJ Phipps - Journal of the American …, 2016 - ACS Publications
The use of noncovalent interactions to direct transition-metal catalysis is a potentially
powerful yet relatively underexplored strategy, with most investigations thus far focusing on …

The emergence of the C–H functionalization strategy in medicinal chemistry and drug discovery

R Jana, HM Begam, E Dinda - Chemical Communications, 2021 - pubs.rsc.org
Owing to the market competitiveness and urgent societal need, an optimum speed of drug
discovery is an important criterion for successful implementation. Despite the rapid ascent of …

Noncovalent interactions in Ir-catalyzed C–H activation: L-shaped ligand for para-selective borylation of aromatic esters

ME Hoque, R Bisht, C Haldar… - Journal of the American …, 2017 - ACS Publications
An efficient strategy for the para-selective borylation of aromatic esters is described. For
achieving high para-selectivity, a new catalytic system has been developed modifying the …