Recent advances in organoactinide chemistry as exemplified by cyclopentadienyl compounds

M Ephritikhine - Organometallics, 2013 - ACS Publications
The ubiquity of the cyclopentadienyl ligand permits us to use its complexes as
representative examples for the description of recent highlights in organometallic and more …

DFT investigations of the magnetic properties of actinide complexes

L Belkhiri, B Le Guennic, A Boucekkine - Magnetochemistry, 2019 - mdpi.com
Over the past 25 years, magnetic actinide complexes have been the object of considerable
attention, not only at the experimental level, but also at the theoretical one. Such systems are …

Electronic Structure and Magneto-Structural Correlations Study of Cu2UL Trinuclear Schiff Base Complexes: A 3d–5f–3d Case

S Meskaldji, L Belkhiri, R Maurice… - The Journal of …, 2023 - ACS Publications
The magnetic properties of trinuclear Schiff base complexes M2AnLi (MII= Zn, Cu; AnIV= Th,
U; Li= Schiff base; i= 1–4, 6, 7, 9), exhibiting the [M (μ-O) 2] 2U core structure with adjacent …

Theoretical investigation of the electronic structure and magnetic properties of oxo-bridged uranyl (V) dinuclear and trinuclear complexes

B Teyar, S Boucenina, L Belkhiri, B Le Guennic… - Inorganic …, 2019 - ACS Publications
The uranyl (V) complexes [UO2 (dbm) 2K (18C6)] 2 (dbm= dibenzoylmethanate) and [UO2
(L)] 3 (L= 2-(4-tolyl)-1, 3-bis (quinolyl) malondiiminate), exhibiting diamond-shaped U2O2 …

Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2012

FT Edelmann - Coordination Chemistry Reviews, 2014 - Elsevier
This review summarizes the progress in organo-f-element chemistry during the year 2012. A
continuing trend in organolanthanide research is a strong emphasis on applications of …

Electronic structure and magnetic properties of dioxo-bridged diuranium complexes with diamond-core structural motifs: a relativistic DFT study

B Teyar, L Belkhiri, K Costuas, A Boucekkine… - Inorganic …, 2016 - ACS Publications
Electronic structures and magnetic properties of the binuclear bis (μ-oxo) UIV/UIV K2 [{((nP,
MeArO) 3tacn) UIV} 2 (μ-O) 2] and UV/UV [{((nP, MeArO) 3tacn) UV} 2 (μ-O) 2](tacn …

Exchange Couplings and Magneto‐Structural Correlations of Trinuclear MII‐UIV‐MII (MII=Co, Ni, Cu) Complexes

L Belkhiri, R Maurice, B Le Guennic… - European Journal of …, 2024 - Wiley Online Library
The magnetic properties of the trinuclear Schiff base complexes M2UL7 (MII= Co, Ni, Cu;
L7= N, N'‐bis (3‐hydroxysalicylidene)‐2, 2‐dimethyl‐1, 3‐propanediamine), exhibiting the …

Synthesis, crystal structure, magnetic properties and DFT calculations of new dihydroxo-bridged binuclear chromium (III) based on monodentate mixed ligand

S Ouilia, C Beghidja, A Beghidja, L Belkhiri… - Inorganica Chimica …, 2018 - Elsevier
A new dihydroxo-bridged binuclear chromium (III) complex [Cr (µ-OH)(Py) 2 (N 3) 2] 2• Py
has been synthesized and characterized by elemental analyses, infrared spectroscopy …

Electronic structure and magnetic properties of naphthalene-and stilbene-diimide-bridged diuranium (V) complexes: a theoretical study

S Boucenina, L Belkhiri, S Meskaldji… - Journal of Molecular …, 2020 - Springer
The magnetic exchange coupling between two diuranium (V) ions exhibiting the 5 f 1-5 f 1
configuration in diimide-bridged complexes [Cp 3 UV] 2 (μ-L)(L= stilbene-, naphthalene …

Redox properties of biscyclopentadienyl uranium (V) imido-halide complexes: a relativistic DFT study

A Elkechai, F Kias, F Talbi, A Boucekkine - Journal of molecular modeling, 2014 - Springer
Calculations of ionization energies (IE) and electron affinities (EA) of a series of
biscyclopentadienyl imido-halide uranium (V) complexes Cp* 2 U (= N–2, 6–i Pr 2–C 6 H …