Size dependence of nanostructures: Impact of bond order deficiency

CQ Sun - Progress in solid state chemistry, 2007 - Elsevier
This report deals with the mechanism behind the unusual behavior of nanostructures in
mechanical strength, thermal stability, acoustics (lattice dynamics), photonics, electronics …

Melting Is Well-Known, but Is It Also Well-Understood?

G de With - Chemical Reviews, 2023 - ACS Publications
Contrary to continuous phase transitions, where renormalization group theory provides a
general framework, for discontinuous phase transitions such a framework seems to be …

Liquid-drop model for the size-dependent melting of low-dimensional systems

KK Nanda, SN Sahu, SN Behera - Physical review A, 2002 - APS
Empirical relations are established between the cohesive energy, surface tension, and
melting temperature of different bulk solids. An expression for the size-dependent melting for …

In situ measurements and modeling of carbon nanotube array growth kinetics during chemical vapor deposition

AA Puretzky, DB Geohegan, S Jesse, IN Ivanov… - Applied Physics A, 2005 - Springer
Direct measurements of carbon nanotube growth kinetics are described based upon time-
resolved reflectivity (TRR) of a HeNe laser beam from vertically aligned nanotube arrays …

Melting thermodynamics of organic nanocrystals

Q Jiang, HX Shi, M Zhao - The journal of chemical physics, 1999 - pubs.aip.org
In 1954, Takagi demonstrated for the first time that ultrafine metallic particles melt below their
corresponding bulk melting temperature. 1 It is now known that the melting temperature of all …

Size-dependent melting of nanoparticles: Hundred years of thermodynamic model

KK Nanda - Pramana, 2009 - Springer
Thermodynamic model first published in 1909, is being used extensively to understand the
size-dependent melting of nanoparticles. Pawlow deduced an expression for the size …

A unifying framework to quantify the effects of substrate interactions, stiffness, and roughness on the dynamics of thin supported polymer films

PZ Hanakata, BA Pazmiño Betancourt… - The Journal of …, 2015 - pubs.aip.org
Changes in the dynamics of supported polymer films in comparison to bulk materials involve
a complex convolution of effects, such as substrate interactions, roughness, and compliance …

Modelling for size-dependent and dimension-dependent melting of nanocrystals

Z Zhang, JC Li, Q Jiang - Journal of Physics D: Applied Physics, 2000 - iopscience.iop.org
A unified model, free of any adjustable parameters, for the size-dependence and dimension-
dependence of melting point depression and superheating of nanocrystals is developed. In …

Size effects on Debye temperature, Einstein temperature, and volume thermal expansion coefficient of nanocrystals

CC Yang, MX **ao, W Li, Q Jiang - Solid state communications, 2006 - Elsevier
Based on a size-dependent root of mean square amplitude (rms) model, the size-dependent
Debye temperatures of nanocrystals are modeled without any adjustable parameter by …

Size-, shape-, and dimensionality-dependent melting temperatures of nanocrystals

HM Lu, PY Li, ZH Cao, XK Meng - The Journal of Physical …, 2009 - ACS Publications
On the basis of a model for size-dependent cohesive energy, the size, shape, and
dimensionality effects on melting temperatures of nanocrystals are modeled in a unified …