[HTML][HTML] Spin state switching in iron coordination compounds

P Gütlich, AB Gaspar, Y Garcia - Beilstein journal of organic …, 2013 - beilstein-journals.org
The article deals with coordination compounds of iron (II) that may exhibit thermally induced
spin transition, known as spin crossover, depending on the nature of the coordinating ligand …

Structure: function relationships in molecular spin-crossover complexes

MA Halcrow - Chemical Society Reviews, 2011 - pubs.rsc.org
Spin-crossover compounds are becoming increasingly popular for device and sensor
applications, and in soft materials, that make use of their switchable colour, paramagnetism …

Spin-crossover iron (II) coordination polymer with fluorescent properties: Correlation between emission properties and spin state

C Lochenie, K Schötz, F Panzer, H Kurz… - Journal of the …, 2018 - ACS Publications
A spin-crossover coordination polymer [Fe (L1)(bipy)] n (where L= a N2O22–coordinating
Schiff base-like ligand bearing a phenazine fluorophore and bipy= 4, 4′-bipyridine) was …

Spin crossover iron complexes with spin transition near room temperature based on nitrogen ligands containing aromatic rings: From molecular design to functional …

Y Zhang, R Torres-Cavanillas, X Yan, Y Zeng… - Chemical Society …, 2024 - pubs.rsc.org
During last decades, significant advances have been made in iron-based spin crossover
(SCO) complexes, with a particular emphasis on achieving reversible and reproducible …

A Two‐Dimensional Iron (II) Coordination Polymer with Synergetic Spin‐Crossover and Luminescent Properties

JY Ge, Z Chen, L Zhang, X Liang, J Su… - Angewandte …, 2019 - Wiley Online Library
Abstract A composite material,{[Fe (L)(TPPE) 0.5]⋅ 3 CH3OH} n, has been constructed by
integrating the spin‐crossover (SCO) subunit FeII {diethyl (E, E)‐2, 2′‐[1, 2‐phenyl‐bis …

How to Switch Spin‐Crossover Metal Complexes at Constant Room Temperature

MM Khusniyarov - Chemistry–A European Journal, 2016 - Wiley Online Library
Spin‐crossover metal complexes represent a highly promising class of molecular switches,
the diverse physicochemical properties of which can be reversibly changed by different …

A fluorescence-detected coordination-induced spin state switch

H Kurz, K Schötz, I Papadopoulos… - Journal of the …, 2021 - ACS Publications
The response of the spin state to in situ variation of the coordination number (CISSS) is a
promising and viable approach to smart sensor materials, yet it suffers to date from …

Spin-crossover in iron (II)-Schiff base complexes

KS Kumar, Y Bayeh, T Gebretsadik, F Elemo… - Dalton …, 2019 - pubs.rsc.org
The spin-crossover (SCO) phenomenon is one of the most prominent examples of bi-stability
in molecular chemistry, and the SCO complexes are proposed for nanotechnological …

Spin crossover–quo vadis?

P Gütlich - European Journal of Inorganic Chemistry, 2013 - Wiley Online Library
This retrospective essay is an attempt to span the bridge over eight decades of research on
spin crossover (SCO), one of the most fascinating dynamic electron structure phenomena of …

Guest‐Dependent Spin‐Transition Behavior of Porous Coordination Polymers

R Ohtani, S Hayami - Chemistry–A European Journal, 2017 - Wiley Online Library
The host–guest composites of Hofmann‐type iron (II) spin‐transition (ST) porous
coordination polymers incorporating guest molecules show guest‐dependent ST behavior in …