Conspectus Catalysts for asymmetric synthesis must be chiral. Metal-based asymmetric
catalysts are typically constructed by assembling chiral ligands around a central metal. In …

The review summarizes the most recent achievements in the chemistry of 2‐vinylindoles and
3‐vinylindoles. In particular, we focus on the behavior of these compounds as dienes in …

A rhodium-based chiral Lewis acid catalyst combined with [Ru (bpy) 3](PF6) 2 as a
photoredox sensitizer allows for the visible-light-activated redox coupling of α-silylamines …

A bis‐cyclometalated rhodium (III) complex catalyzes a visible‐light‐activated
enantioselective α‐amination of 2‐acyl imidazoles with up to 99% yield and 98% ee. The …

A newly prepared chiral-at-metal Rh (III) complex-catalyzed, highly efficient enantioselective
decarboxylative Michael addition of β-keto acids with α, β-unsaturated 2-acyl imidazoles or …

Synthetic access to previously elusive single enantiomers of an octahedral chiral-at-metal
rhodium (III) complex containing two cyclometalated 2-phenylbenzothiazoles and two …

Chiral Rh (III) complex catalyzed highly efficient enantioselective cyclopropanation of α, β-
unsaturated 2-acyl imidazoles or pyridine with 2-bromomalonate is developed to generate …

A bis-cyclometalated iridium (III) complex with metal-centered chirality catalyzes the
enantioselective transfer hydrogenation of ketones with high enantioselectivities at low …

The covalent immobilization of a chiral-at-metal bis-cyclometalated iridium (III) catalyst on a
solid support is reported, and its catalytic activity has been investigated. As a catalyst …

A strategy for the synthesis of multisubstituted hydrocarbazoles has been developed through
(3+ 2)-annulation of p-quinamines and arynes. In this way, new analogs of hydrocarbazoles …