Oxide glasses under pressure: Recent insights from experiments and simulations

T Du, SS Sørensen, T To, MM Smedskjaer - Journal of Applied Physics, 2022 - pubs.aip.org
Deciphering the structure-property relations of densified oxide glasses is a problem of
longstanding interest. For example, it is important for understanding the fracture mechanism …

A chemical perspective on high pressure crystal structures and properties

JS Tse - National Science Review, 2020 - academic.oup.com
The general availability of third generation synchrotron sources has ushered in a new era of
high pressure research. The crystal structure of materials under compression can now be …

[HTML][HTML] Influence of high-pressure on the short-range structure of Ca or Na aluminoborosilicate glasses from 11B and 27Al solid-state NMR

S Soudani, M Paris, Y Morizet - Journal of Non-Crystalline Solids, 2024 - Elsevier
The present study investigates the boron and aluminium speciation of aluminoborosilicate
glasses synthesised under ambient to high-pressure conditions (up to 2.0 GPa) using 11 B …

[HTML][HTML] Persistent homology: A tool to understand medium-range order glass structure

SS Sørensen, T Du, CAN Biscio, L Fajstrup… - Journal of Non …, 2022 - Elsevier
Glass structure remains puzzling to scientists, especially due to the challenges in
characterizing their structural order beyond the first coordination shell, ie, the so-called …

Degree of permanent densification in oxide glasses upon extreme compression up to 24 GPa at room temperature

SK Lee, KY Mun, YH Kim, J Lhee… - The Journal of …, 2020 - ACS Publications
During the decompression of plastically deformed glasses at room temperature, some
aspects of irreversible densification may be preserved. This densification has been primarily …

Vibrational spectroscopy and density of K 2 O–B 2 O 3–GeO 2 glasses with variable B/Ge ratio

ON Koroleva, MV Shtenberg, RT Zainullina… - Physical Chemistry …, 2019 - pubs.rsc.org
Glasses of the K2O–B2O3–GeO2 system were studied by means of Raman and IR
spectroscopy. The density of the samples was measured and the dependence of the molar …

First-Principles Studies on the Structure and B–O Coordination of B2O3 Glass at High Pressure

H Kuang, Y Pan, JS Tse - The Journal of Physical Chemistry C, 2024 - ACS Publications
The structures of amorphous materials at extreme pressures can be very different from those
of their crystalline counterparts. Recent nonresonant inelastic scattering experiments on …

Pressure-Driven Changes in the Electronic Bonding Environment of GeO2 Glass above Megabar Pressures

YH Kim, YS Yi, HI Kim, P Chow, Y **ao… - Journal of the …, 2022 - ACS Publications
Noncrystalline oxides under pressure undergo gradual structural modifications, highlighted
by the formation of a dense noncrystalline network topology. The nature of the densified …

Oxygen Quadclusters in Glass above Megabar Pressures up to 160 GPa Revealed by X-Ray Raman Scattering

SK Lee, YH Kim, YS Yi, P Chow, Y **ao, C Ji… - Physical Review Letters, 2019 - APS
As oxygen may occupy a major volume of oxides, a densification of amorphous oxides
under extreme compression is dominated by reorganization of oxygen during compression …

Probing medium-range order in oxide glasses at high pressure

SK Lee, AC Lee, JJ Kweon - The Journal of Physical Chemistry …, 2021 - ACS Publications
Densification in glassy networks has traditionally been described in terms of short-range
structures, such as how atoms are coordinated and how the coordination polyhedron is …