Fe (II) redox chemistry in the environment

J Huang, A Jones, TD Waite, Y Chen, X Huang… - Chemical …, 2021 - ACS Publications
Iron (Fe) is the fourth most abundant element in the earth's crust and plays important roles in
both biological and chemical processes. The redox reactivity of various Fe (II) forms has …

Consider the anoxic microsite: acknowledging and appreciating spatiotemporal redox heterogeneity in soils and sediments

EM Lacroix, M Aeppli, K Boye, E Brodie… - ACS Earth and Space …, 2023 - ACS Publications
Reduction–oxidation (redox) reactions underlie essentially all biogeochemical cycles. Like
most soil properties and processes, redox is spatiotemporally heterogeneous. However …

Iron-mediated organic matter decomposition in humid soils can counteract protection

C Chen, SJ Hall, E Coward, A Thompson - Nature communications, 2020 - nature.com
Soil organic matter (SOM) is correlated with reactive iron (Fe) in humid soils, but Fe also
promotes SOM decomposition when oxygen (O2) becomes limited. Here we quantify Fe …

Active iron phases regulate the abiotic transformation of organic carbon during redox fluctuation cycles of paddy soil

N Chen, Q Fu, T Wu, P Cui, G Fang, C Liu… - … science & technology, 2021 - ACS Publications
Iron (Fe) phases are tightly linked to the preservation rather than the loss of organic carbon
(OC) in soil; however, during redox fluctuations, OC may be lost due to Fe phase-mediated …

Electron transfer, atom exchange, and transformation of iron minerals in soils: the influence of soil organic matter

C Chen, Y Dong, A Thompson - Environmental Science & …, 2023 - ACS Publications
Despite substantial experimental evidence of electron transfer, atom exchange, and
mineralogical transformation during the reaction of Fe (II) aq with synthetic Fe (III) minerals …

[HTML][HTML] Biogeochemical cycling of iron (hydr-) oxides and its impact on organic carbon turnover in coastal wetlands: A global synthesis and perspective

C Yu, S **e, Z Song, S **a, ME Åström - Earth-Science Reviews, 2021 - Elsevier
Coastal wetlands host large and dynamic reservoirs of organic carbon (C) and are also
biogeochemical hotspots for a wide range of Fe (hydr-) oxides with different chemical …

Active iron species driven hydroxyl radicals formation in oxygenation of different paddy soils: Implications to polycyclic aromatic hydrocarbons degradation

N Chen, D Huang, G Liu, L Chu, G Fang, C Zhu… - Water Research, 2021 - Elsevier
The frequently occurring redox fluctuations in paddy soil are critical to the cycling of redox-
sensitive elements (eg, iron (Fe) and carbon) due to the driving of microbial processes …

Microbially driven iron cycling facilitates organic carbon accrual in decadal biochar-amended soil

H He, J Liu, Z Shu, Y Chen, Z Pan, C Peng… - Environmental …, 2024 - ACS Publications
Soil organic carbon (SOC) is pivotal for both agricultural activities and climate change
mitigation, and biochar stands as a promising tool for bolstering SOC and curtailing soil …

[HTML][HTML] Mineral-mediated stability of organic carbon in soil and relevant interaction mechanisms

Z Xu, DCW Tsang - Eco-Environment & Health, 2024 - Elsevier
Soil, the largest terrestrial carbon reservoir, is central to climate change and relevant
feedback to environmental health. Minerals are the essential components that contribute to …

Long-term application of agricultural amendments regulate hydroxyl radicals production during oxygenation of paddy soils

N Chen, D Huang, Y Zeng, J Wang, G Liu… - Environmental …, 2024 - ACS Publications
Hydroxyl radicals (• OH) play a significant role in contaminant transformation and element
cycling during redox fluctuations in paddy soil. However, these important processes might …