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Surface coordination chemistry of atomically dispersed metal catalysts
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …
catalysts, have been widely investigated during the past two decades. The atomic dispersion …
Metal-organic frameworks as emerging platform for supporting isolated single-site catalysts
Isolated heterogeneous single-site catalysts have been attracted great interest in diverse
catalytic reactions because of their uniform and distinct geometric and electronic structure …
catalytic reactions because of their uniform and distinct geometric and electronic structure …
Identification of the active complex for CO oxidation over single-atom Ir-on-MgAl2O4 catalysts
Supported single atoms provide an opportunity to design new heterogeneous catalysts
while optimizing the utilization of noble metals. However, identification of the active single …
while optimizing the utilization of noble metals. However, identification of the active single …
Heterogeneous iridium single-atom molecular-like catalysis for epoxidation of ethylene
H Yang, X Wang, Q Liu, A Huang, X Zhang… - Journal of the …, 2023 - ACS Publications
Develo** efficient and simple catalysts to reveal the key scientific issues in the
epoxidation of ethylene has been a long-standing goal for chemists, whereas a …
epoxidation of ethylene has been a long-standing goal for chemists, whereas a …
In-situ synthesis of single-atom Ir by utilizing metal-organic frameworks: An acid-resistant catalyst for hydrogenation of levulinic acid to γ-valerolactone
The hydrogenation of levulinic acid (LA) to γ-valerolactone (GVL) is a key reaction for the
production of renewable chemicals and fuels, wherein acid-resistant and robust catalysts …
production of renewable chemicals and fuels, wherein acid-resistant and robust catalysts …
Tuning Zr6 Metal–Organic Framework (MOF) Nodes as Catalyst Supports: Site Densities and Electron-Donor Properties Influence Molecular Iridium Complexes as …
The Zr6 nodes of the metal–organic frameworks (MOFs) UiO-66 and UiO-67 are metal oxide
clusters of atomic precision and can be used as catalyst supports. The bonding sites on …
clusters of atomic precision and can be used as catalyst supports. The bonding sites on …
Low temperature oxidation of ethane to oxygenates by oxygen over iridium-cluster catalysts
Direct selective oxidation of light alkanes, such as ethane, into value-added chemical
products under mild reaction conditions remains a challenge in both industry and academia …
products under mild reaction conditions remains a challenge in both industry and academia …
Homogeneity of surface sites in supported single-site metal catalysts: assessment with band widths of metal carbonyl infrared spectra
Determining and controlling the uniformity of isolated metal sites on surfaces of supports are
central goals in investigations of single-site catalysts because well-defined species provide …
central goals in investigations of single-site catalysts because well-defined species provide …
Single-step selective oxidation of methane to methanol in the aqueous phase on iridium-based catalysts
In this work, one-step conversion of methane to methanol using molecular oxygen as the
oxidant in the presence of CO in aqueous solutions on copper or palladium promoted Ir-ZSM …
oxidant in the presence of CO in aqueous solutions on copper or palladium promoted Ir-ZSM …
A site-isolated mononuclear iridium complex catalyst supported on MgO: characterization by spectroscopy and aberration-corrected scanning transmission electron …
Supported mononuclear iridium complexes with ethene ligands were prepared by the
reaction of Ir (C2H4) 2 (acac)(acac is CH3COCHCOCH3) with highly dehydroxylated MgO …
reaction of Ir (C2H4) 2 (acac)(acac is CH3COCHCOCH3) with highly dehydroxylated MgO …