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Process-directed self-assembly of copolymers: Results of and challenges for simulation studies
M Müller - Progress in Polymer Science, 2020 - Elsevier
Process-directed self-assembly refers to processes that reproducibly trap the kinetics of
structure formation that ensues after a sudden change (“quench”) of the thermodynamic …
structure formation that ensues after a sudden change (“quench”) of the thermodynamic …
High χ–Low N Block Polymers: How Far Can We Go?
C Sinturel, FS Bates, MA Hillmyer - 2015 - ACS Publications
Block polymers incorporating highly incompatible segments are termed “high χ” polymers,
where χ is the Flory–Huggins interaction parameter. These materials have attracted a great …
where χ is the Flory–Huggins interaction parameter. These materials have attracted a great …
Thermal processing of diblock copolymer melts mimics metallurgy
Small-angle x-ray scattering experiments conducted with compositionally asymmetric low
molar mass poly (isoprene)-b-poly (lactide) diblock copolymers reveal an extraordinary …
molar mass poly (isoprene)-b-poly (lactide) diblock copolymers reveal an extraordinary …
Frank–Kasper phases in block polymers
KD Dorfman - Macromolecules, 2021 - ACS Publications
The discovery of the Frank–Kasper σ phase in diblock copolymer and tetrablock terpolymer
melts catalyzed a renewed interest over the past decade in understanding particle-forming …
melts catalyzed a renewed interest over the past decade in understanding particle-forming …
[HTML][HTML] Field-theoretic simulations for block copolymer melts using the partial saddle-point approximation
Field-theoretic simulations (FTS) provide an efficient technique for investigating fluctuation
effects in block copolymer melts with numerous advantages over traditional particle-based …
effects in block copolymer melts with numerous advantages over traditional particle-based …
[HTML][HTML] Field theoretic approach for block polymer melts: SCFT and FTS
MW Matsen - The Journal of Chemical Physics, 2020 - pubs.aip.org
This perspective addresses the development of polymer field theory for predicting the
equilibrium phase behavior of block polymer melts. The approach is tailored to the high …
equilibrium phase behavior of block polymer melts. The approach is tailored to the high …
Chain length effect on thermal transport in amorphous polymers and a structure–thermal conductivity relation
The physics of thermal transport in polymers is important in many applications, such as in
heat exchangers and electronics packaging. Even though thermal conductivity models for …
heat exchangers and electronics packaging. Even though thermal conductivity models for …
Diffusion in lamellae, cylinders, and double gyroid block copolymer nanostructures
We study transport of penetrants through nanoscale morphologies motivated by common
block copolymer morphologies, using confined random walks and coarse-grained …
block copolymer morphologies, using confined random walks and coarse-grained …
Effects of tailored dispersity on the self-assembly of dimethylsiloxane–methyl methacrylate block co-oligomers
The effect of dispersity on block polymer self-assembly was studied in the monodisperse
limit using a combination of synthetic chemistry, matrix-assisted laser desorption ionization …
limit using a combination of synthetic chemistry, matrix-assisted laser desorption ionization …
Similarity of Polymer Packing in Melts Is Dictated by N̅
J Qin - Macromolecules, 2024 - ACS Publications
The literature usage of the invariant degree of polymerization N̅ is surveyed and
categorized according to the physical arguments involved. By providing rationales based on …
categorized according to the physical arguments involved. By providing rationales based on …