Pincer complexes are useful tools for organic synthesis. Their high stability and easy
functionalization have allowed the development of novel catalytic systems that have had a …

Hydrogenation of nitriles into primary amines is a crucial chemical reaction due to the
importance of primary amines in the plastic, pharmaceutical, and agrochemical industry …

Novel well-defined NNP and PNP manganese pincer complexes have been synthetized and
fully characterized. The catalyst Mn-2 containing an imidazolyaminolphosphino ligand …

Herein, we describe a selective cobalt‐catalyzed chemodivergent transfer hydrogenation of
nitriles to synthesize primary, secondary, and tertiary amines. The solvent effect plays a key …

The selective hydrogenation of nitriles to primary amines using a bench-stable cobalt
precatalyst under 4 atm of H2 is reported herein. The catalyst precursor was reduced in situ …

A general procedure for the catalytic hydrogenation of nitriles to primary amines by using a
non‐noble metal‐based system is presented. Co (acac) 3 in combination with tris [2 …

Low-valent molybdenum PNP pincer complexes were studied as catalysts for the
semihydrogenation of alkynes. For that purpose, t Bu-substituted PNP complexes PNP t …

Cooperative dual site activation of boranes by redox-active 1, 3-N, S-chelated ruthenium
species, mer-[PR3 {κ2-N, S-(L)} 2Ru {κ1-S-(L)}],(mer-2a: R= Cy, mer-2b: R= Ph; L …

Selective hydrogenation of nitriles to secondary imines catalyzed by an iron complex, the
pincer complex (iPr-PNP) Fe (H) Br (CO), in the presence of catalytic base, is reported. A …

Manganese‐catalyzed hydrogenation reactions have aroused widespread interest in recent
years. Among the catalytic systems described, especially PNP‐and NNP–Mn pincer …