Quantum‐mechanical condensed matter simulations with CRYSTAL

R Dovesi, A Erba, R Orlando… - Wiley …, 2018 - Wiley Online Library
The latest release of the Crystal program for solid‐state quantum‐mechanical ab initio
simulations is presented. The program adopts atom‐centered Gaussian‐type functions as a …

Dispersion-corrected mean-field electronic structure methods

S Grimme, A Hansen, JG Brandenburg… - Chemical …, 2016 - ACS Publications
Mean-field electronic structure methods like Hartree–Fock, semilocal density functional
approximations, or semiempirical molecular orbital (MO) theories do not account for long …

GFN2-xTB—An accurate and broadly parametrized self-consistent tight-binding quantum chemical method with multipole electrostatics and density-dependent …

C Bannwarth, S Ehlert, S Grimme - Journal of chemical theory and …, 2019 - ACS Publications
An extended semiempirical tight-binding model is presented, which is primarily designed for
the fast calculation of structures and noncovalent interaction energies for molecular systems …

A robust and accurate tight-binding quantum chemical method for structures, vibrational frequencies, and noncovalent interactions of large molecular systems …

S Grimme, C Bannwarth… - Journal of chemical theory …, 2017 - ACS Publications
We propose a novel, special purpose semiempirical tight binding (TB) method for the
calculation of structures, vibrational frequencies, and noncovalent interactions of large …

Robust atomistic modeling of materials, organometallic, and biochemical systems

S Spicher, S Grimme - Angewandte Chemie International …, 2020 - Wiley Online Library
Modern chemistry seems to be unlimited in molecular size and elemental composition. Metal‐
organic frameworks or biological macromolecules involve complex architectures and a large …

B97-3c: A revised low-cost variant of the B97-D density functional method

JG Brandenburg, C Bannwarth, A Hansen… - The Journal of chemical …, 2018 - pubs.aip.org
A revised version of the well-established B97-D density functional approximation with
general applicability for chemical properties of large systems is proposed. Like B97-D, it is …

Consistent structures and interactions by density functional theory with small atomic orbital basis sets

S Grimme, JG Brandenburg, C Bannwarth… - The Journal of chemical …, 2015 - pubs.aip.org
A density functional theory (DFT) based composite electronic structure approach is
proposed to efficiently compute structures and interaction energies in large chemical …

[PDF][PDF] Report on the sixth blind test of organic crystal structure prediction methods

AM Reilly, RI Cooper, CS Adjiman… - … Section B: Structural …, 2016 - journals.iucr.org
The sixth blind test of organic crystal structure prediction (CSP) methods has been held, with
five target systems: a small nearly rigid molecule, a polymorphic former drug candidate, a …

Stabilizing and modulating color by copigmentation: Insights from theory and experiment

P Trouillas, JC Sancho-García, V De Freitas… - Chemical …, 2016 - ACS Publications
Natural anthocyanin pigments/dyes and phenolic copigments/co-dyes form noncovalent
complexes, which stabilize and modulate (in particular blue, violet, and red) colors in …

Computational studies of synthetically relevant homogeneous organometallic catalysis involving Ni, Pd, Ir, and Rh: an overview of commonly employed DFT methods …

T Sperger, IA Sanhueza, I Kalvet… - Chemical …, 2015 - ACS Publications
The field of organometallic catalysis has attracted considerable interest from both academia
and industry due to its broad applications in synthetic transformations. Pd, Ni, Rh, and Ir …