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Recent advances in aqueous actinide chemistry and thermodynamics
This Review presents an overview of recent advances in aqueous actinide chemistry and
thermodynamics. It addresses actinides from thorium to curium and covers three main areas …
thermodynamics. It addresses actinides from thorium to curium and covers three main areas …
A review of the retention mechanisms of redox-sensitive radionuclides in multi-barrier systems
The deep geological disposal concept is widely accepted by the scientific community for the
storage of high activity level nuclear waste. It uses a multi-barrier system to isolate …
storage of high activity level nuclear waste. It uses a multi-barrier system to isolate …
Binding mechanisms of radionuclides to cement
Radionuclide solubility is one of the factors that can determine the 'source term'for potential
migration to the far field. Hence, the mechanisms of immobilisation of radionuclides in …
migration to the far field. Hence, the mechanisms of immobilisation of radionuclides in …
Measurement and modeling of the surface potential evolution of hydrated cement pastes as a function of degradation
Hydrated cement pastes (HCP) have a high affinity with a lot of (radio) toxic products and
can be used as waste confining materials. In cementitious media, elements are removed …
can be used as waste confining materials. In cementitious media, elements are removed …
[HTML][HTML] Density functional theory study of the crystal structure and infrared spectrum of a synthetized ettringite mineral
F Colmenero, AM Fernández, O Almendros-Ginestà… - Minerals, 2024 - mdpi.com
One of the most important hydration phases of Portland cement is ettringite, a calcium sulfo-
aluminate mineral (C a 6 A l 2 (OH) 12 (SO 4) 3· 26 H 2 O) showing a great capacity of …
aluminate mineral (C a 6 A l 2 (OH) 12 (SO 4) 3· 26 H 2 O) showing a great capacity of …
U (VI) sorption on Ca-bentonite at (hyper) alkaline conditions–spectroscopic investigations of retention mechanisms
Environmental conditions in deep geological repositories for radioactive waste may involve
high pH values due to the degradation of concrete. However, the U (VI) sorption at such …
high pH values due to the degradation of concrete. However, the U (VI) sorption at such …
Adsorption of gluconate and uranyl on CSH phases: Combination of wet chemistry experiments and molecular dynamics simulations for the binary systems
As a first step in develo** better molecular scale understanding of the effects of organic
additives on the adsorption and mobility of radionuclides in cement under conditions of …
additives on the adsorption and mobility of radionuclides in cement under conditions of …
Uptake of anionic radionuclides onto degraded cement pastes and competing effect of organic ligands
Hardened cement pastes (HCP) present a high affinity with a lot of radionuclides (RN) and
can be used as waste confining materials in radioactive waste repository. Indeed, in …
can be used as waste confining materials in radioactive waste repository. Indeed, in …
Analysis of uranium sorption in a laboratory column experiment using a reactive transport and surface complexation model
The transport and retardation of radioactive elements in hyper-alkaline conditions of
radioactive waste repositories is a challenging field that is still poorly understood. In this …
radioactive waste repositories is a challenging field that is still poorly understood. In this …
Determination of uranium (VI) sorbed species in calcium silicate hydrate phases: A laser-induced luminescence spectroscopy and batch sorption study
Batch sorption experiments and time-resolved luminescence spectroscopy investigations
were carried out to study the U (VI) speciation in calcium silicate hydrates for varying …
were carried out to study the U (VI) speciation in calcium silicate hydrates for varying …