Direct arylation via cleavage of activated and unactivated CH bonds

M Miura, M Nomura - Cross-Coupling Reactions: A Practical Guide, 2002 - Springer
Palladium catalyzed direct coupling of aryl halides not only with various carbon nucleophiles
having acidic CH bonds, but also with aromatic and heteroaromatic compounds …

Nickel‐Catalyzed Intermolecular Asymmetric Addition of Aryl Iodides across Aldehydes

Z Zhu, J **ao, M Li, Z Shi - Angewandte Chemie International …, 2022 - Wiley Online Library
Enantioenriched alcohols comprise much of the framework of organic molecules. Here, we
first report that chiral nickel complexes can catalyze the intermolecular enantioselective …

Ni‐Catalyzed Divergent Synthesis of 2‐Benzazepine Derivatives via Tunable Cyclization and 1, 4‐Acyl Transfer Triggered by Amide N‐C Bond Cleavage

Y **, X Li, Q Pan, W Kong - … Chemie International Edition, 2022 - Wiley Online Library
Ligand‐directed divergent synthesis can transform common starting materials into distinct
molecular scaffolds by simple tuning different ligands. This strategy enables the rapid …

Palladium-catalyzed arylative carbon− carbon bond cleavage of α, α-disubstituted arylmethanols

Y Terao, H Wakui, T Satoh, M Miura… - Journal of the American …, 2001 - ACS Publications
Transition metal-catalyzed organic reactions involving the cleavage of CC single bonds
have recently attracted much attention. 1 Although the cleavage is energetically unfavorable …

Carbopalladation of nitriles: synthesis of 2, 3-diarylindenones and polycyclic aromatic ketones by the Pd-catalyzed annulation of alkynes and bicyclic alkenes by 2 …

AA Pletnev, Q Tian, RC Larock - The Journal of Organic Chemistry, 2002 - ACS Publications
2-Iodobenzonitrile, its derivatives, and various heterocyclic analogues undergo palladium
(0)-catalyzed annulation onto diarylacetylenes or bicyclic alkenes to afford 2, 3 …

Carbon monoxide free aminocarbonylation of aryl and alkenyl iodides using DMF as an amide source

K Hosoi, K Nozaki, T Hiyama - Organic Letters, 2002 - ACS Publications
Carbon Monoxide Free Aminocarbonylation of Aryl and Alkenyl Iodides Using DMF as an
Amide Source | Organic Letters Recently Viewedclose modal ACS ACS Publications C&EN …

Exploiting the divergent reactivity of aryl–palladium intermediates for the rapid assembly of fluorene and phenanthrene derivatives

YB Zhao, B Mariampillai, DA Candito… - Angewandte Chemie …, 2009 - Wiley Online Library
They all fall down: The value of domino processes can be greatly enhanced when the
possibility exists for one to selectively diverge from a common intermediate. In preliminary …

Arylation reactions via CH bond cleavage

M Miura, T Satoh - Palladium in Organic Synthesis: -/-, 2005 - Springer
Various carbon nucleophiles having acidic C–H bonds, including active methylene
compounds, ketones, aldehydes, esters, and so on, are arylated with aryl halides under …

Tertiary Carbinamine Synthesis by Rhodium‐Catalyzed [3+ 2] Annulation of N‐Unsubstituted Aromatic Ketimines and Alkynes

ZM Sun, SP Chen, P Zhao - Chemistry–A European Journal, 2010 - Wiley Online Library
A convenient and waste‐free synthesis of indene‐based tertiary carbinamines by rhodium‐
catalyzed imine/alkyne [3+ 2] annulation is described. Under the optimized conditions of 0.5 …

Redox‐Neutral Coupling between Two C(sp3)−H Bonds Enabled by 1,4‐Palladium Shift for the Synthesis of Fused Heterocycles

R Rocaboy, I Anastasiou, O Baudoin - Angewandte Chemie, 2019 - Wiley Online Library
The intramolecular coupling of two C (sp3)− H bonds to forge a C (sp3)− C (sp3) bond is
enabled by 1, 4‐Pd shift from a trisubstituted aryl bromide. Contrary to most C (sp3)− C (sp3) …