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Conjugated nanohoops incorporating donor, acceptor, hetero‐or polycyclic aromatics
In the last 13 years several synthetic strategies were developed that provide access to [n]
cycloparaphenylenes ([n] CPPs) and related conjugated nanohoops. A number of potential …
cycloparaphenylenes ([n] CPPs) and related conjugated nanohoops. A number of potential …
Antiaromatic covalent organic frameworks based on dibenzopentalenes
Despite their inherent instability, 4 n π systems have recently received significant attention
due to their unique optical and electronic properties. In dibenzopentalene (DBP) …
due to their unique optical and electronic properties. In dibenzopentalene (DBP) …
Conjugated nanohoop polymers based on antiaromatic dibenzopentalenes for charge storage in organic batteries
With their bent π‐systems, cyclic conjugation and inherent cavities, conjugated nanohoops
are attractive for organic electronics applications. For ease of processing and morphological …
are attractive for organic electronics applications. For ease of processing and morphological …
[n]Cyclodibenzopentalenes as Antiaromatic Curved Nanocarbons with High Strain and Strong Fullerene Binding
Conjugated nanohoops provide a platform to study structure–property relationships; they are
attractive hosts for supramolecular chemistry as well as promising candidates as new …
attractive hosts for supramolecular chemistry as well as promising candidates as new …
Towards clustered carbonyl cations [M 3 (CO) 14] 2+(M= Ru, Os): the need for innocent deelectronation
To access the hitherto almost unknown class of clustered transition metal carbonyl cations,
the trimetal dodecacarbonyls M3 (CO) 12 (M= Ru, Os) were reacted with the oxidant Ag+ …
the trimetal dodecacarbonyls M3 (CO) 12 (M= Ru, Os) were reacted with the oxidant Ag+ …
Chiral dibenzopentalene‐based conjugated Nanohoops through stereoselective synthesis
Conjugated nanohoops allow to investigate the effect of radial conjugation and bending on
the involved π‐systems. They can possess unexpected optoelectronic properties and their …
the involved π‐systems. They can possess unexpected optoelectronic properties and their …
Enantiopure nanohoops through racemic resolution of diketo [n] CPPs by chiral derivatization as precursors to DBP [n] CPPs
Strained conjugated nanohoops are attractive synthetic targets due to the bending of their π-
system, which leads to intriguing optoelectronic properties, among others. By incorporating …
system, which leads to intriguing optoelectronic properties, among others. By incorporating …
Bisazapentalene dication: global aromaticity and open-shell singlet ground state
Antiaromatic moieties fused in polycyclic π-conjugated molecules usually exhibit strong
localized antiaromaticiy. Herein, we reported the synthesis and properties of a …
localized antiaromaticiy. Herein, we reported the synthesis and properties of a …
Utilizing the Perfluoronaphthalene Radical Cation as a Selective Deelectronator to Access a Variety of Strongly Oxidizing Reactive Cations
A selective deelectronation reagent with very high potential of+ 2.00 (solution)/+ 2.41 V
(solid‐state) vs. Fc+/0 and based on a room temperature stable perfluoronaphthalene …
(solid‐state) vs. Fc+/0 and based on a room temperature stable perfluoronaphthalene …
Increased Antiaromaticity through Pentalene Connection in [n]Cyclo-1,5-dibenzopentalenes
Conjugated nanohoops incorporating nonalternant hydrocarbons have altered
optoelectronic properties compared to [n] cycloparaphenylenes or other purely aromatic …
optoelectronic properties compared to [n] cycloparaphenylenes or other purely aromatic …