New strategies for the synthesis of aliphatic azides

P Sivaguru, Y Ning, X Bi - Chemical Reviews, 2021 - ACS Publications
Aliphatic azides are a versatile class of compounds found in a variety of biologically active
pharmaceuticals. These compounds are also recognized as useful precursors for the …

Recent advances in tandem selenocyclization and tellurocyclization with alkenes and alkynes

K Sun, X Wang, C Li, H Wang, L Li - Organic Chemistry Frontiers, 2020 - pubs.rsc.org
Seleno-containing heterocycles exist widely in pharmaceutical molecules and the skeletons
of natural products. The addition of organoselenium to alkenes and alkynes via …

Transition‐Metal‐Catalyzed Three‐Component Difunctionalizations of Alkenes

JS Zhang, L Liu, T Chen, LB Han - Chemistry–An Asian Journal, 2018 - Wiley Online Library
Three‐component reactions can directly convert three reactants into the desired products in
one pot and thus greatly shorten the synthetic path. Recently, transition‐metal catalysis has …

Selective difunctionalization of unactivated aliphatic alkenes enabled by a metal–metallaaromatic catalytic system

FH Cui, Y Hua, YM Lin, J Fei, LH Gao… - Journal of the …, 2022 - ACS Publications
The design of organometallic catalysts is crucial in the development of catalytic reactions.
Herein, we describe a heterometallic [Os-Cu] complex with the characteristics of bimetallics …

Organoselenium compounds: Chemistry and applications in organic synthesis

JM Sonego, SI De Diego, SH Szajnman… - … A European Journal, 2023 - Wiley Online Library
Selenium, originally described as a toxin, turns out to be a crucial trace element for life that
appears as selenocysteine and its dimer, selenocystine. From the point of view of drug …

Electrochemical aminoselenation and oxyselenation of styrenes with hydrogen evolution

L Sun, Y Yuan, M Yao, H Wang, D Wang, M Gao… - Organic …, 2019 - ACS Publications
The use of additive-free conditions is an ideal approach to prepare organoselenium
reagents from readily available unsaturated substrates. Thus, we report the electro-induced …

Electrochemical Difunctionalization of Olefines: Access to Selenomethyl‐Substituted Cyclic Ethers or Lactones

XJ Meng, PF Zhong, YM Wang… - Advanced Synthesis …, 2020 - Wiley Online Library
A metal‐and oxidant‐free electrochemical method for preparing selenomethyl‐substituted
cyclic ethers or lactones via difunctionalization of olefines is presented. A series of …

[BOOK][B] Organoselenium chemistry

T Wirth - 2018 - orca.cardiff.ac.uk
Organoselenium chemistry has been established as a valuable research area in synthetic
and medicinal chemistry. After the discovery of the selenoxide elimination reaction in the …

Three-component aminoselenation of alkenes via visible-light enabled Fe-catalysis

B Huang, Y Li, C Yang, W **a - Green Chemistry, 2020 - pubs.rsc.org
A visible-light-enabled, iron-catalyzed three-component reaction for difunctionalization of
alkenes with amines and diselenides has been developed, wherein a photo-excitable Fe …

“Green is the color”: An update on ecofriendly aspects of organoselenium chemistry

JB Azeredo, F Penteado, V Nascimento, L Sancineto… - Molecules, 2022 - mdpi.com
Organoselenium compounds have been successfully applied in biological, medicinal and
material sciences, as well as a powerful tool for modern organic synthesis, attracting the …