Siloxane coordination revisited: Si− O bond character, reactivity and magnificent molecular shapes
Siloxanes have evolved into a multi‐million dollar business due to their manifold of
commercial and industrial applications. As siloxanes have high hydrophobicity, low basicity …
commercial and industrial applications. As siloxanes have high hydrophobicity, low basicity …
Recent contributions to the coordination chemistry of beryllium
MR Buchner - Chemistry–A European Journal, 2019 - Wiley Online Library
Given the alleged extreme toxicity of beryllium and its compounds, it is the least investigated
nonradioactive element. However, beryllium exhibits unique properties among the elements …
nonradioactive element. However, beryllium exhibits unique properties among the elements …
Beryllium coordination chemistry and its implications on the understanding of metal induced immune responses
MR Buchner - Chemical Communications, 2020 - pubs.rsc.org
The inhalation of beryllium and its compounds can cause the development of chronic
beryllium disease in susceptible individuals. This is caused by a distinct autoimmune …
beryllium disease in susceptible individuals. This is caused by a distinct autoimmune …
A fusion of molecular imprinting technology and siloxane chemistry: A way to advanced hybrid nanomaterials
M Woźnica, M Sobiech, P Luliński - Nanomaterials, 2023 - mdpi.com
Molecular imprinting technology is a well-known strategy to synthesize materials with a
predetermined specificity. For fifty years, the “classical” approach assumed the creation of …
predetermined specificity. For fifty years, the “classical” approach assumed the creation of …
Chelation of lithium ion with crown ether for eliminating adverse effects caused by Li-TFSI/tBP do** system in Spiro-OMeTAD
Z Wan, H Lu, J Yang, Y Zhang, F Lin, J ** system for the hole transport material Spiro-OMeTAD in typical nip structure …
Unsupported metal silyl ether coordination
J Pahl, H Elsen, A Friedrich, S Harder - Chemical Communications, 2018 - pubs.rsc.org
Simple silyl ethers like O (SiMe3) 2 in contrast to normal ethers are inert to metal bonding;
however, a “naked”, highly Lewis-acidic, cationic Mg species enforces complexation. DFT …
however, a “naked”, highly Lewis-acidic, cationic Mg species enforces complexation. DFT …
From the discovery of field ionization to field desorption and liquid injection field desorption/ionization-mass spectrometry—a journey from principles and applications …
JH Gross - European Journal of Mass Spectrometry, 2020 - journals.sagepub.com
The discovery of the ionizing effect of strong electric fields in the order of volts per Ångstrom
in the early 1950s eventually led to the development of field ionization-mass spectrometry …
in the early 1950s eventually led to the development of field ionization-mass spectrometry …
Crown Ether Complexes of Alkali‐Metal Chlorides from SO2
The structures of alkali‐metal chloride SO2 solvates (Li–Cs) in conjunction with 12‐crown‐4
or 1, 2‐disila‐12‐crown‐4 show strong discrepancies, despite the structural similarity of the …
or 1, 2‐disila‐12‐crown‐4 show strong discrepancies, despite the structural similarity of the …
The coordination behaviour and reactivity of partially silicon based crown ethers towards beryllium chloride
Through reactions of 1, 2-disila [12] crown-4 or 1, 2-disila-benzo [12] crown-4 ethers with
BeCl2 eight-membered Be–O-heterocycles, which are annulated by two six-membered Be …
BeCl2 eight-membered Be–O-heterocycles, which are annulated by two six-membered Be …
Synthesis and coordination ability of a partially silicon based crown ether
K Reuter, G Thiele, T Hafner, F Uhlig… - Chemical …, 2016 - pubs.rsc.org
The first hybrid crown ether with two adjacent disilane fragments was synthesized through
reaction of O (Si2Me4Cl) 2 (3) with O (C2H4OH) 2. By means of DFT calculations, the …
reaction of O (Si2Me4Cl) 2 (3) with O (C2H4OH) 2. By means of DFT calculations, the …