Active template synthesis

R Jamagne, MJ Power, ZH Zhang, G Zango… - Chemical Society …, 2024 - pubs.rsc.org
The active template synthesis of mechanically interlocked molecular architectures exploits
the dual ability of various structural elements (metals or, in the case of metal-free active …

Phenanthroline based rotaxanes: recent developments in syntheses and applications

S Rashid, Y Yoshigoe, S Saito - RSC advances, 2022 - pubs.rsc.org
The advancements in the field of mechanically interlocked molecular systems (MIMs) has
concurrently restructured the material chemistry frontiers and provided ample scope to …

Mechanical Bond Enhanced Lithium Halide Ion‐Pair Binding by Halogen Bonding Heteroditopic Rotaxanes

VK Munasinghe, J Pancholi… - … A European Journal, 2022 - Wiley Online Library
A family of novel halogen bonding (XB) and hydrogen bonding (HB) heteroditopic [2]
rotaxane host systems constructed by active metal template (AMT) methodology, were …

NDI-integrated rotaxane/catenane and their interactions with anions

M Nandi, S Bej, P Ghosh - Dalton Transactions, 2022 - pubs.rsc.org
Complexation of alkali and alkaline earth metal ions with the heteroditopic Phen-ester oxy-
ether macrocyclic wheel (PhenMC) is established for the synthesis of interlocked molecular …

Electrochemical switching in mechanically interlocked molecules (MIMs)

A Bhadani, M Kathiresan - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
Mechanically interlocked molecules (MIMs) which include rotaxanes and catenanes are
formed by the mechanical linking of two or more components and have significant potential …

A Cd (II) and Zn (II) selective naphthyl based [2] rotaxane acts as an exclusive Zn (II) sensor upon further functionalization with pyrene

S Bej, M Nandi, P Ghosh - Dalton Transactions, 2021 - pubs.rsc.org
A new multi-functional [2] rotaxane, ROTX, has been synthesized via a Cu (I) catalysed
azide–alkyne cycloaddition reaction between Ni (II) templated azide terminated …

Development of fluorophoric [2] pseudorotaxanes and [2] rotaxane: selective sensing of Zn (II)

S Bej, M Nandi, P Ghosh - Organic & Biomolecular Chemistry, 2022 - pubs.rsc.org
Fluorophoric [2] pseudorotaxanes {NiPR1 (ClO4) 2–NiPR3 (ClO4) 2} are synthesized by
utilizing newly designed fluorophoric bidentate ligands (L1–L3) and a heteroditopic …

Orientation of the α-CD component of [2] rotaxanes affects their specific molecular recognition behaviour

T Iwamoto, S Miyagawa, M Naito… - Organic Chemistry …, 2021 - pubs.rsc.org
In this study we synthesized a pair of orientationally isomeric [2] rotaxanes (1 and 2)
featuring an α-cyclodextrin (α-CD) as the macrocyclic component and phenylurea and 2 …

From construction to application of a new generation of interlocked molecules composed of heteroditopic wheels

M Nandi, S Bej, T Jana, P Ghosh - Chemical Communications, 2023 - pubs.rsc.org
Over the last few decades, research on mechanically interlocked molecules has significantly
evolved owing to their unique structural features and interesting properties. A substantial …