The Enigma of Methanol Synthesis by Cu/ZnO/Al2O3-Based Catalysts

A Beck, MA Newton, LGA van de Water… - Chemical …, 2024 - ACS Publications
The activity and durability of the Cu/ZnO/Al2O3 (CZA) catalyst formulation for methanol
synthesis from CO/CO2/H2 feeds far exceed the sum of its individual components. As such …

Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO2 Hydrogenation Processes

A Álvarez, A Bansode, A Urakawa, AV Bavykina… - Chemical …, 2017 - ACS Publications
The recent advances in the development of heterogeneous catalysts and processes for the
direct hydrogenation of CO2 to formate/formic acid, methanol, and dimethyl ether are …

From CO2 to Methanol on Cu/ZnO/Al2O3 Industrial Catalyst. What Do We Know about the Active Phase and the Reaction Mechanism?

G Pacchioni - ACS Catalysis, 2024 - ACS Publications
For more than half a century, the industrial production of methanol in the world has been
based on a heterogeneous Cu/ZnO/Al2O3 catalyst where Cu nanoparticles are dispersed …

Dilute alloys based on Au, Ag, or Cu for efficient catalysis: from synthesis to active sites

JD Lee, JB Miller, AV Shneidman, L Sun… - Chemical …, 2022 - ACS Publications
The development of new catalyst materials for energy-efficient chemical synthesis is critical
as over 80% of industrial processes rely on catalysts, with many of the most energy-intensive …

Methanol Synthesis from CO2 Hydrogenation

M Bowker - ChemCatChem, 2019 - Wiley Online Library
In the future we will be phasing out the use of fossil fuels in favour of more sustainable forms
of energy, especially solar derived forms such as hydroelectric, wind and photovoltaic …

O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts

MM Montemore, MA Van Spronsen, RJ Madix… - Chemical …, 2017 - ACS Publications
The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …

Heterogeneous catalysis

R Schlögl - Angewandte Chemie International Edition, 2015 - Wiley Online Library
A heterogeneous catalyst is a functional material that continually creates active sites with its
reactants under reaction conditions. These sites change the rates of chemical reactions of …

Review of the synthesis, transfer, characterization and growth mechanisms of single and multilayer graphene

HC Lee, WW Liu, SP Chai, AR Mohamed, A Aziz… - RSC …, 2017 - pubs.rsc.org
Graphene has emerged as the most popular topic in the active research field since
graphene's discovery in 2004 by Andrei Geim and Kostya Novoselov. Since then, graphene …

Mechanism of Methanol Synthesis on Cu through CO2 and CO Hydrogenation

LC Grabow, M Mavrikakis - Acs Catalysis, 2011 - ACS Publications
We present a comprehensive mean-field microkinetic model for the methanol synthesis and
water-gas-shift (WGS) reactions that includes novel reaction intermediates, such as formic …

[КНИГА][B] Comprehensive handbook of chemical bond energies

YR Luo - 2007 - taylorfrancis.com
Understanding the energy it takes to build or break chemical bonds is essential for scientists
and engineers in a wide range of innovative fields, including catalysis, nanomaterials …