CRYSTAL23: A program for computational solid state physics and chemistry

A Erba, JK Desmarais, S Casassa… - Journal of Chemical …, 2022 - ACS Publications
The Crystal program for quantum-mechanical simulations of materials has been bridging the
realm of molecular quantum chemistry to the realm of solid state physics for many years …

The density matrix renormalization group in chemistry and molecular physics: Recent developments and new challenges

A Baiardi, M Reiher - The Journal of Chemical Physics, 2020 - pubs.aip.org
In the past two decades, the density matrix renormalization group (DMRG) has emerged as
an innovative new method in quantum chemistry relying on a theoretical framework very …

[PDF][PDF] Anharmonic vibrational properties by a fully automated second-order perturbative approach

V Barone - Journal of Chemical Physics, 2005 - 140.123.79.88
Infrared IR and Raman spectroscopies are among the most powerful techniques for
characterizing medium size molecules, but proper assignment of spectra is often not …

Accuracy and interpretability: The devil and the holy grail. New routes across old boundaries in computational spectroscopy

C Puzzarini, J Bloino, N Tasinato, V Barone - Chemical reviews, 2019 - ACS Publications
The past decade has witnessed an increasing interaction between experiment and theory in
the field of molecular spectroscopy. On the computational side, ongoing developments of …

Fully anharmonic IR and Raman spectra of medium-size molecular systems: accuracy and interpretation

V Barone, M Biczysko, J Bloino - Physical Chemistry Chemical Physics, 2014 - pubs.rsc.org
Computation of full infrared (IR) and Raman spectra (including absolute intensities and
transition energies) for medium-and large-sized molecular systems beyond the harmonic …

Vibrational zero-point energies and thermodynamic functions beyond the harmonic approximation

V Barone - The Journal of chemical physics, 2004 - pubs.aip.org
This paper compares harmonic and anharmonic zero-point energies and thermodynamic
functions for a number of molecules of small and medium size. Anharmonic corrections …

A second-order perturbation theory route to vibrational averages and transition properties of molecules: General formulation and application to infrared and vibrational …

J Bloino, V Barone - The Journal of Chemical Physics, 2012 - pubs.aip.org
A general formulation to compute anharmonic vibrational averages and transition properties
at the second-order of perturbation theory is derived from the Rayleigh-Schrödinger …

Variational quantum approaches for computing vibrational energies of polyatomic molecules

JM Bowman, T Carrington, HD Meyer - Molecular Physics, 2008 - Taylor & Francis
In this article, we review state-of-the-art methods for computing vibrational energies of
polyatomic molecules using quantum mechanical, variationally-based approaches. We …

General perturbative approach for spectroscopy, thermodynamics, and kinetics: Methodological background and benchmark studies

J Bloino, M Biczysko, V Barone - Journal of Chemical Theory and …, 2012 - ACS Publications
A general second-order perturbative approach based on resonance-and threshold-free
computations of vibrational properties is introduced and validated. It starts from the …

Vibrational coupled cluster theory

O Christiansen - The Journal of chemical physics, 2004 - pubs.aip.org
The theory and first implementation of a vibrational coupled cluster VCC method for
calculations of the vibrational structure of molecules is presented. Different methods for …