Abstract Metal-organic Frameworks (MOFs) represent a growing field of materials that are
receiving widespread attention due to their fascinating structures, intriguing properties, and …

Structural insight into reactive species can be achieved via strategies such as matrix
isolation in frozen glasses, whereby species are kinetically trapped, or by confinement within …

This paper describes the identification of specific host–guest interactions between basic
gases (NH3, CD3CN, and pyridine) and four topologically similar 2-dimensional (2D) metal …

Metal–organic frameworks (MOFs) can act as a platform for the heterogenization of
molecular catalysts, providing improved stability, allowing easy catalyst recovery and a route …

Single‐crystal X‐ray crystallography is employed to characterize the reaction species of a
full catalytic carbonylation cycle within a MnII‐based metal–organic framework (MOF) …

Although metal–organic frameworks (MOFs) have been shown to catalyse a wide range of
reactions, understanding the influence of nanoscale structuralisation (eg crystal size and …

Coordination polymers and metal–organic frameworks: materials by design | Philosophical
Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences logo …

Site-selective organic transformations are commonly required in the synthesis of complex
molecules. By employing a bespoke metal–organic framework (MOF, 1·[Mn (CO) 3N3]), in …

Postsynthetic metal exchange represents a powerful synthetic method to generate metal–
organic frameworks (MOFs) that are not accessible through direct synthesis, yet it is often …

Obtaining structural information for highly reactive metal-based species can provide
valuable insight into important chemical transformations or catalytic processes. Trap** …