The Scholl reaction as a powerful tool for synthesis of curved polycyclic aromatics
The past decade has witnessed remarkable success in the synthesis of curved polycyclic
aromatics through Scholl reactions which enable oxidative aryl–aryl coupling even in …
aromatics through Scholl reactions which enable oxidative aryl–aryl coupling even in …
Nanographenes and graphene nanoribbons as multitalents of present and future materials science
As cut-outs from a graphene sheet, nanographenes (NGs) and graphene nanoribbons
(GNRs) are ideal cases with which to connect the world of molecules with that of bulk carbon …
(GNRs) are ideal cases with which to connect the world of molecules with that of bulk carbon …
Structurally constrained boron-, nitrogen-, silicon-, and phosphorus-centered polycyclic π-conjugated systems
M Hirai, N Tanaka, M Sakai, S Yamaguchi - Chemical reviews, 2019 - ACS Publications
Incorporation of main group elements into the π-conjugated frameworks is a sophisticated
strategy to alter the fundamental nature of the parent conjugated π-systems, giving rise to …
strategy to alter the fundamental nature of the parent conjugated π-systems, giving rise to …
Helical bilayer nanographenes: impact of the helicene length on the structural, electrochemical, photophysical, and chiroptical properties
P Izquierdo-García, JM Fernández-García… - Journal of the …, 2023 - ACS Publications
Helical bilayer nanographenes (HBNGs) are chiral π-extended aromatic compounds
consisting of two π–π stacked hexabenzocoronenes (HBCs) joined by a helicene, thus …
consisting of two π–π stacked hexabenzocoronenes (HBCs) joined by a helicene, thus …
Fluorescent cyclophanes and their applications
With the serendipitous discovery of crown ethers by Pedersen more than half a century ago
and the subsequent introduction of host–guest chemistry and supramolecular chemistry by …
and the subsequent introduction of host–guest chemistry and supramolecular chemistry by …
Small size, big impact: recent progress in bottom‐up synthesized nanographenes for optoelectronic and energy applications
Bottom‐up synthesized graphene nanostructures, including 0D graphene quantum dots and
1D graphene nanoribbons, have recently emerged as promising candidates for efficient …
1D graphene nanoribbons, have recently emerged as promising candidates for efficient …
Molecular carbons: How far can we go?
The creation and development of carbon nanomaterials promoted material science
significantly. Bottom-up synthesis has emerged as an efficient strategy to synthesize …
significantly. Bottom-up synthesis has emerged as an efficient strategy to synthesize …
[HTML][HTML] Transition metal impurities in carbon-based materials: Pitfalls, artifacts and deleterious effects
From carbides in steel to cobalt–carbon covalent bonds in vitamin B 12, transition metal (TM)–
carbon interactions play a critical role in so many aspects of human life that we rarely realize …
carbon interactions play a critical role in so many aspects of human life that we rarely realize …
Helical Synthetic Nanographenes with Atomic Precision
Y Zhu, J Wang - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Understanding and harnessing the properties of nanoscale molecular entities
are considered as new frontiers in basic chemistry. In this regard, synthetic nanographene …
are considered as new frontiers in basic chemistry. In this regard, synthetic nanographene …
Synthetic chiral molecular nanographenes: the key figure of the racemization barrier
JM Fernández-García, P Izquierdo-García… - Chemical …, 2022 - pubs.rsc.org
Chirality is one of the most intriguing concepts of chemistry, involving living systems and,
more recently, materials science. In particular, the bottom-up synthesis of molecular …
more recently, materials science. In particular, the bottom-up synthesis of molecular …