The Scholl reaction as a powerful tool for synthesis of curved polycyclic aromatics

Y Zhang, SH Pun, Q Miao - Chemical Reviews, 2022 - ACS Publications
The past decade has witnessed remarkable success in the synthesis of curved polycyclic
aromatics through Scholl reactions which enable oxidative aryl–aryl coupling even in …

Nanographenes and graphene nanoribbons as multitalents of present and future materials science

Y Gu, Z Qiu, K Müllen - Journal of the American Chemical …, 2022 - ACS Publications
As cut-outs from a graphene sheet, nanographenes (NGs) and graphene nanoribbons
(GNRs) are ideal cases with which to connect the world of molecules with that of bulk carbon …

Structurally constrained boron-, nitrogen-, silicon-, and phosphorus-centered polycyclic π-conjugated systems

M Hirai, N Tanaka, M Sakai, S Yamaguchi - Chemical reviews, 2019 - ACS Publications
Incorporation of main group elements into the π-conjugated frameworks is a sophisticated
strategy to alter the fundamental nature of the parent conjugated π-systems, giving rise to …

Helical bilayer nanographenes: impact of the helicene length on the structural, electrochemical, photophysical, and chiroptical properties

P Izquierdo-García, JM Fernández-García… - Journal of the …, 2023 - ACS Publications
Helical bilayer nanographenes (HBNGs) are chiral π-extended aromatic compounds
consisting of two π–π stacked hexabenzocoronenes (HBCs) joined by a helicene, thus …

Fluorescent cyclophanes and their applications

I Roy, AHG David, PJ Das, JP David… - Chemical Society …, 2022 - pubs.rsc.org
With the serendipitous discovery of crown ethers by Pedersen more than half a century ago
and the subsequent introduction of host–guest chemistry and supramolecular chemistry by …

Small size, big impact: recent progress in bottom‐up synthesized nanographenes for optoelectronic and energy applications

Z Liu, S Fu, X Liu, A Narita, P Samorì, M Bonn… - Advanced …, 2022 - Wiley Online Library
Bottom‐up synthesized graphene nanostructures, including 0D graphene quantum dots and
1D graphene nanoribbons, have recently emerged as promising candidates for efficient …

Molecular carbons: How far can we go?

MW Wang, W Fan, X Li, Y Liu, Z Li, W Jiang, J Wu… - Acs Nano, 2023 - ACS Publications
The creation and development of carbon nanomaterials promoted material science
significantly. Bottom-up synthesis has emerged as an efficient strategy to synthesize …

[HTML][HTML] Transition metal impurities in carbon-based materials: Pitfalls, artifacts and deleterious effects

W Kiciński, S Dyjak - Carbon, 2020 - Elsevier
From carbides in steel to cobalt–carbon covalent bonds in vitamin B 12, transition metal (TM)–
carbon interactions play a critical role in so many aspects of human life that we rarely realize …

Helical Synthetic Nanographenes with Atomic Precision

Y Zhu, J Wang - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Understanding and harnessing the properties of nanoscale molecular entities
are considered as new frontiers in basic chemistry. In this regard, synthetic nanographene …

Synthetic chiral molecular nanographenes: the key figure of the racemization barrier

JM Fernández-García, P Izquierdo-García… - Chemical …, 2022 - pubs.rsc.org
Chirality is one of the most intriguing concepts of chemistry, involving living systems and,
more recently, materials science. In particular, the bottom-up synthesis of molecular …