Single-electron lanthanide-lanthanide bonds inside fullerenes toward robust redox-active molecular magnets
Conspectus A characteristic phenomenon of lanthanide–fullerene interactions is the transfer
of metal valence electrons to the carbon cage. With early lanthanides such as La, a …
of metal valence electrons to the carbon cage. With early lanthanides such as La, a …
Functional metallofullerene materials and their applications in nanomedicine, magnetics, and electronics
T Wang, C Wang - Small, 2019 - Wiley Online Library
Endohedral metallofullerenes exhibit combined properties from carbon cages as well as
internal metal moieties and have great potential in a wide range of applications as molecule …
internal metal moieties and have great potential in a wide range of applications as molecule …
Magnetic Hysteresis at 10 K in Single Molecule Magnet Self‐Assembled on Gold
Tremendous progress in the development of single molecule magnets (SMMs) raises the
question of their device integration. On this route, understanding the properties of low …
question of their device integration. On this route, understanding the properties of low …
Metamagnetic transition and a loss of magnetic hysteresis caused by electron trap** in monolayers of single-molecule magnet Tb 2@ C 79 N
Realization of stable spin states in surface-supported magnetic molecules is crucial for their
applications in molecular spintronics, memory storage or quantum information processing. In …
applications in molecular spintronics, memory storage or quantum information processing. In …
Prospects for laser cooling of polyatomic molecules with increasing complexity
Optical cycling transitions and direct laser cooling have recently been demonstrated for a
number of alkaline-earth dimers and trimer molecules. This is made possible by diagonal …
number of alkaline-earth dimers and trimer molecules. This is made possible by diagonal …
Impact of Zeeman and hyperfine interactions on the magnetic properties of paramagnetic metal Ions: I. Local interactions of the electron spin
YE Kandrashkin - Journal of Magnetic Resonance, 2024 - Elsevier
The anisotropic Zeeman interaction of an ion, and the strong hyperfine interaction with its
own nucleus, can significantly influence its interactions with the local environment. These …
own nucleus, can significantly influence its interactions with the local environment. These …
Shape-adaptive single-molecule magnetism and hysteresis up to 14 K in oxide clusterfullerenes Dy 2 O@ C 72 and Dy 2 O@ C 74 with fused pentagon pairs and …
G Velkos, W Yang, YR Yao, SM Sudarkova, XY Liu… - Chemical …, 2020 - pubs.rsc.org
Dysprosium oxide clusterfullerenes Dy2O@ Cs (10528)–C72 and Dy2O@ C2 (13333)–C74
are synthesized and characterized by single-crystal X-ray diffraction. Carbon cages of both …
are synthesized and characterized by single-crystal X-ray diffraction. Carbon cages of both …
Single‐Molecule Magnets DyM2N@C80 and Dy2MN@C80 (M=Sc, Lu): The Impact of Diamagnetic Metals on Dy3+ Magnetic Anisotropy, Dy⋅⋅⋅Dy Coupling …
The substitution of scandium in fullerene single‐molecule magnets (SMMs) DySc2N@ C80
and Dy2ScN@ C80 by lutetium has been studied to explore the influence of the diamagnetic …
and Dy2ScN@ C80 by lutetium has been studied to explore the influence of the diamagnetic …
Advances in Regioselective Functionalization of Endohedral Metallofullerenes†
Comprehensive Summary Endohedral metallofullerenes (EMFs) are a family of molecules
with metal clusters or ions encapsulated inside a fullerene cage. Their unique structures …
with metal clusters or ions encapsulated inside a fullerene cage. Their unique structures …
Multiple locations of boron atoms in the exohedral and endohedral fullerene
AV Bibikov, AV Nikolaev, IV Bodrenko, PV Borisyuk… - Physical Review A, 2022 - APS
We study theoretically the bound states of one and two boron atoms in the exohedral and
endohedral C 60 fullerene. The optimal position of one boron atom is found above the …
endohedral C 60 fullerene. The optimal position of one boron atom is found above the …