Complex structures and morphologies in nature endow materials with unexpected
properties and extraordinary functions. Biotemplating is an emerging strategy for replicating …

Controlling regio-and enantioselectivity in C–H functionalization reactions is of paramount
importance due to their versatile synthetic utilities. Herein, we describe a new approach for …

Engineered metalloenzymes represent promising catalysts for stereoselective C–H
functionalization reactions. Recently, P450 enzymes have been evolved to allow for new-to …

Azepines and their saturated azepane counterparts are important moieties in bioactive
molecules but are under-represented in current drug screening libraries. Herein, we report a …

This paper describes iron/photoredox dual-catalyzed acyl nitrene formation and the use of
acyl nitrene in constructing various C–O bonds towards phthalides. The developed reaction …

A silver-catalyzed aminative dearomatization of naphthols has been developed and
integrated into a stepwise approach for subsequent skeletal diversifications including ring …

Transition-metal-catalyzed C–H aminations via nitrene transfer processes are powerful
synthetic methods to construct valuable amines. Over the past decade, significant efforts in …

An efficient PdII-and RhIII-controlled site-selective C–H bond alkynylation of
imidazopyridines using (bromoethynyl) triisopropylsilane is disclosed. The divergent …

Cobalt-bisoxazolinephosphine-catalyzed regio-and enantioselective allylic amination of
racemic n-propyl allylic carbonate and aniline was investigated by DFT calculations at the …

Electrochemical C− H functionalizations are attractive transformations, as they are capable
of avoiding the use of transition metals, pre‐oxidized precursors, or suprastoichiometric …