Progress in design and applications of supramolecular assembly of 2, 2′: 6′, 2 ″-terpyridine-based first row d-block elements

BZ Momeni, N Davarzani, J Janczak, N Ma… - Coordination Chemistry …, 2024 - Elsevier
Abstract 2, 2′: 6′, 2 ″-Terpyridine (tpy)-based transition metal complexes have continued
to receive attention due to their outstanding features and promising industrial and …

Terpyridine‐Based 3D Discrete Metallosupramolecular Architectures

X Yu, C Guo, S Lu, Z Chen, H Wang… - Macromolecular Rapid …, 2022 - Wiley Online Library
Abstract Terpyridine (tpy)‐based 3D discrete metallosupramolecular architectures, which
are often inspired by polyhedral geometry and the biological structures found in nature, have …

Multiple-stimuli fluorescent responsive metallo-organic helicated cage arising from monomer and excimer emission

Z Zhang, Q Bai, Z Zhai, Q Long, E Han, H Zhao… - Nature …, 2024 - nature.com
Effectively regulating monomer and excimer emission in a singular supramolecular
luminous platform is challenging due to high difficulty of precise control over its aggregation …

Anion‐Regulated Hierarchical Self‐Assembly and Chiral Induction of Metallo‐Tetrahedra

Q Bai, YM Guan, T Wu, Y Liu, Z Zhai… - Angewandte Chemie …, 2023 - Wiley Online Library
The precise control over hierarchical self‐assembly of superstructures relying on the
elaboration of multiple noncovalent interactions between basic building blocks is both …

Dynamic supramolecular snub cubes

H Wu, Y Wang, L Đorđević, P Kundu, S Bhunia… - Nature, 2025 - nature.com
Mimicking the superstructures and properties of spherical biological encapsulants such as
viral capsids and ferritin offers viable pathways to understand their chiral assemblies and …

Interconversion of Highly Entangled Polyhedra into Concave Polyhedra by Nitrate‐Induced Ternary Coordination

Y Domoto, M Abe, GR Genov, Z Yu… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract Entangled (M3L2) n polyhedral complexes represent a unique class of
supramolecular architectures that are stabilized by relatively weak metal–acetylene …

Guest binding is governed by multiple stimuli in low-symmetry metal-organic cages containing bis-pyridyl (imine) vertices

Y Yang, TK Ronson, PCP Teeuwen, Y Du, J Zheng… - Chem, 2025 - cell.com
Inspired by natural systems, metal-organic cages with well-defined shapes and cavities can
be tuned for different guest-binding functions. Here, we report the construction of two types …

Adaptive and Dynamic Nonintertwined Assembly of Rigid and Flexible Rings

T Wang, X He, J Xu, D Shen, L Mei, G Xu… - CCS …, 2025 - chinesechemsoc.org
Biomorphic supramolecular assemblies formed through the collaboration of rigid and
flexible elements, akin to bones and ligaments, play a crucial role in constructing advanced …

Metallo-supramolecular hexagonal wreath with four switchable states based on a pH-responsive tridentate ligand

P Su, B Wei, C Guo, Y Hu, R Tang… - Journal of the …, 2023 - ACS Publications
In biological systems, many biomacromolecules (eg, heme proteins) are capable of
switching their states reversibly in response to external stimuli, endowing these natural …

Steric Control over Interligand Dihedrals and Splay Leads to the Formation of FeII6L6 and FeII8L8 Antiprisms

Y Yang, Y Du, TK Ronson, JR Nitschke - CCS Chemistry, 2024 - chinesechemsoc.org
Macrocycles have found uses in guest capture, sensing, and porous materials, motivating
the development of new methods for their synthesis. Here we report the construction of two …