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Progress in design and applications of supramolecular assembly of 2, 2′: 6′, 2 ″-terpyridine-based first row d-block elements
Abstract 2, 2′: 6′, 2 ″-Terpyridine (tpy)-based transition metal complexes have continued
to receive attention due to their outstanding features and promising industrial and …
to receive attention due to their outstanding features and promising industrial and …
Terpyridine‐Based 3D Discrete Metallosupramolecular Architectures
X Yu, C Guo, S Lu, Z Chen, H Wang… - Macromolecular Rapid …, 2022 - Wiley Online Library
Abstract Terpyridine (tpy)‐based 3D discrete metallosupramolecular architectures, which
are often inspired by polyhedral geometry and the biological structures found in nature, have …
are often inspired by polyhedral geometry and the biological structures found in nature, have …
Multiple-stimuli fluorescent responsive metallo-organic helicated cage arising from monomer and excimer emission
Z Zhang, Q Bai, Z Zhai, Q Long, E Han, H Zhao… - Nature …, 2024 - nature.com
Effectively regulating monomer and excimer emission in a singular supramolecular
luminous platform is challenging due to high difficulty of precise control over its aggregation …
luminous platform is challenging due to high difficulty of precise control over its aggregation …
Anion‐Regulated Hierarchical Self‐Assembly and Chiral Induction of Metallo‐Tetrahedra
Q Bai, YM Guan, T Wu, Y Liu, Z Zhai… - Angewandte Chemie …, 2023 - Wiley Online Library
The precise control over hierarchical self‐assembly of superstructures relying on the
elaboration of multiple noncovalent interactions between basic building blocks is both …
elaboration of multiple noncovalent interactions between basic building blocks is both …
Dynamic supramolecular snub cubes
Mimicking the superstructures and properties of spherical biological encapsulants such as
viral capsids and ferritin offers viable pathways to understand their chiral assemblies and …
viral capsids and ferritin offers viable pathways to understand their chiral assemblies and …
Interconversion of Highly Entangled Polyhedra into Concave Polyhedra by Nitrate‐Induced Ternary Coordination
Abstract Entangled (M3L2) n polyhedral complexes represent a unique class of
supramolecular architectures that are stabilized by relatively weak metal–acetylene …
supramolecular architectures that are stabilized by relatively weak metal–acetylene …
Guest binding is governed by multiple stimuli in low-symmetry metal-organic cages containing bis-pyridyl (imine) vertices
Inspired by natural systems, metal-organic cages with well-defined shapes and cavities can
be tuned for different guest-binding functions. Here, we report the construction of two types …
be tuned for different guest-binding functions. Here, we report the construction of two types …
Adaptive and Dynamic Nonintertwined Assembly of Rigid and Flexible Rings
T Wang, X He, J Xu, D Shen, L Mei, G Xu… - CCS …, 2025 - chinesechemsoc.org
Biomorphic supramolecular assemblies formed through the collaboration of rigid and
flexible elements, akin to bones and ligaments, play a crucial role in constructing advanced …
flexible elements, akin to bones and ligaments, play a crucial role in constructing advanced …
Metallo-supramolecular hexagonal wreath with four switchable states based on a pH-responsive tridentate ligand
P Su, B Wei, C Guo, Y Hu, R Tang… - Journal of the …, 2023 - ACS Publications
In biological systems, many biomacromolecules (eg, heme proteins) are capable of
switching their states reversibly in response to external stimuli, endowing these natural …
switching their states reversibly in response to external stimuli, endowing these natural …
Steric Control over Interligand Dihedrals and Splay Leads to the Formation of FeII6L6 and FeII8L8 Antiprisms
Macrocycles have found uses in guest capture, sensing, and porous materials, motivating
the development of new methods for their synthesis. Here we report the construction of two …
the development of new methods for their synthesis. Here we report the construction of two …