Radical species are significant in modern chemistry. Their unique chemical bonding and
novel physicochemical properties play significant roles not only in fundamental chemistry …

The empty pz-orbital of a three-coordinate organoboron compound leads to its electron-
deficient properties, which make it an excellent π-acceptor in conjugated organic …

Substituted dysprosocenium complexes of the type [Dy (Cp R) 2]+ exhibit slow magnetic
relaxation at cryogenic temperatures and have emerged as top-performing single-molecule …

Boron has one valence electron less than a carbon atom and an available vacant pz orbital.
The incorporation of sp2‐hybridized boron atoms into the host lattice of a polycyclic aromatic …

Shortly after their discovery at the end of the 80s, stable singlet carbenes have been
recognized as excellent ligands for transition metal based catalysts, and as organo-catalysts …

The conventional methods for preparing alkyl boronates often necessitate anhydrous and
demanding reaction conditions. Herein, a new, operationally simple decarboxylative …

Boron, a group 13 element, has several characteristic structural and electronic features: 1)
trivalent boron compounds usually adopt a trigonal planar geometry; 2) due to the presence …

Most of the chemical and biological processes involving the fixation and transformation of
small molecules have long been exclusive for metal complexes. Meanwhile, the last …

Radicals are ubiquitously involved in numerous chemical and biological processes. They
exhibit unique chemical bonding and physical properties applicable to functional materials …

(Hetero) arene-fused boroles are a class of compounds containing a 5-membered boron
diene-ring. Based on their molecular framework, the (hetero) arene-fused boroles can be …