Flory-type theories of polymer chains under different external stimuli
YA Budkov, MG Kiselev - Journal of Physics: Condensed Matter, 2017 - iopscience.iop.org
In this Review, we present a critical analysis of various applications of the Flory-type theories
to a theoretical description of the conformational behavior of single polymer chains in dilute …
to a theoretical description of the conformational behavior of single polymer chains in dilute …
Statistical field theory of ion–molecular solutions
YA Budkov - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
In this article, I summarize my theoretical developments in the statistical field theory of salt
solutions of zwitterionic and multipolar molecules. Based on the Hubbard–Stratonovich …
solutions of zwitterionic and multipolar molecules. Based on the Hubbard–Stratonovich …
Tuning chain interaction entropy in complex coacervation using polymer stiffness, architecture, and salt valency
Oppositely-charged polyelectrolytes can undergo a liquid–liquid phase separation in a salt
solution, resulting in a polymer-dense 'coacervate'phase that has found use in a wide range …
solution, resulting in a polymer-dense 'coacervate'phase that has found use in a wide range …
Conformational Behavior of a Single Dipolar Chain under Stretching Force
TY Merzliakova, YD Gordievskaya… - Macromolecules, 2023 - ACS Publications
The stretching of a single dipolar chain by a tensile force acting on the chain end is studied
using molecular dynamics simulations and theoretical considerations. In both theory and …
using molecular dynamics simulations and theoretical considerations. In both theory and …
Nonlocal statistical field theory of dipolar particles in electrolyte solutions
YA Budkov - Journal of Physics: Condensed Matter, 2018 - iopscience.iop.org
We present a nonlocal statistical field theory of a dilute electrolyte solution with a small
additive of dipolar particles. We postulate that every dipolar particle is associated with an …
additive of dipolar particles. We postulate that every dipolar particle is associated with an …
An interplay of electrostatic and excluded volume interactions in the conformational behavior of a dipolar chain: theory and computer simulations
The effect of an interplay between electrostatic and excluded volume interactions on the
conformational behavior of a dipolar chain has been studied theoretically and by means of …
conformational behavior of a dipolar chain has been studied theoretically and by means of …
[HTML][HTML] The effective χ parameter in polarizable polymeric systems: One-loop perturbation theory and field-theoretic simulations
We derive the effective Flory-Huggins parameter in polarizable polymeric systems, within a
recently introduced polarizable field theory framework. The incorporation of bead …
recently introduced polarizable field theory framework. The incorporation of bead …
Theory of self-coacervation in semi-dilute and concentrated zwitterionic polymer solutions
Based on the random phase approximation, we develop a molecular theory of self-
coacervation in zwitterionic polymer solutions. We show that the interplay between the …
coacervation in zwitterionic polymer solutions. We show that the interplay between the …
Models of the conformational behavior of polymers in mixed solvents
Theoretical models of the conformational behavior of flexible polymer chains in mixed
solvents enunciated in the world literature during the last decade are critically reviewed …
solvents enunciated in the world literature during the last decade are critically reviewed …
Aggregation of flexible polyelectrolytes: Phase diagram and dynamics
Similarly charged polymers in solution, known as polyelectrolytes, are known to form
aggregated structures in the presence of oppositely charged counterions. Understanding the …
aggregated structures in the presence of oppositely charged counterions. Understanding the …