Flory-type theories of polymer chains under different external stimuli

YA Budkov, MG Kiselev - Journal of Physics: Condensed Matter, 2017 - iopscience.iop.org
In this Review, we present a critical analysis of various applications of the Flory-type theories
to a theoretical description of the conformational behavior of single polymer chains in dilute …

Statistical field theory of ion–molecular solutions

YA Budkov - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
In this article, I summarize my theoretical developments in the statistical field theory of salt
solutions of zwitterionic and multipolar molecules. Based on the Hubbard–Stratonovich …

Tuning chain interaction entropy in complex coacervation using polymer stiffness, architecture, and salt valency

TK Lytle, CE Sing - Molecular Systems Design & Engineering, 2018 - pubs.rsc.org
Oppositely-charged polyelectrolytes can undergo a liquid–liquid phase separation in a salt
solution, resulting in a polymer-dense 'coacervate'phase that has found use in a wide range …

Conformational Behavior of a Single Dipolar Chain under Stretching Force

TY Merzliakova, YD Gordievskaya… - Macromolecules, 2023 - ACS Publications
The stretching of a single dipolar chain by a tensile force acting on the chain end is studied
using molecular dynamics simulations and theoretical considerations. In both theory and …

Nonlocal statistical field theory of dipolar particles in electrolyte solutions

YA Budkov - Journal of Physics: Condensed Matter, 2018 - iopscience.iop.org
We present a nonlocal statistical field theory of a dilute electrolyte solution with a small
additive of dipolar particles. We postulate that every dipolar particle is associated with an …

An interplay of electrostatic and excluded volume interactions in the conformational behavior of a dipolar chain: theory and computer simulations

YD Gordievskaya, YA Budkov, EY Kramarenko - Soft matter, 2018 - pubs.rsc.org
The effect of an interplay between electrostatic and excluded volume interactions on the
conformational behavior of a dipolar chain has been studied theoretically and by means of …

[HTML][HTML] The effective χ parameter in polarizable polymeric systems: One-loop perturbation theory and field-theoretic simulations

DJ Grzetic, KT Delaney, GH Fredrickson - The Journal of Chemical …, 2018 - pubs.aip.org
We derive the effective Flory-Huggins parameter in polarizable polymeric systems, within a
recently introduced polarizable field theory framework. The incorporation of bead …

Theory of self-coacervation in semi-dilute and concentrated zwitterionic polymer solutions

YA Budkov, PE Brandyshev, NN Kalikin - Soft Matter, 2023 - pubs.rsc.org
Based on the random phase approximation, we develop a molecular theory of self-
coacervation in zwitterionic polymer solutions. We show that the interplay between the …

Models of the conformational behavior of polymers in mixed solvents

YA Budkov, AL Kolesnikov - Polymer Science, Series C, 2018 - Springer
Theoretical models of the conformational behavior of flexible polymer chains in mixed
solvents enunciated in the world literature during the last decade are critically reviewed …

Aggregation of flexible polyelectrolytes: Phase diagram and dynamics

AM Tom, R Rajesh, S Vemparala - The Journal of chemical physics, 2017 - pubs.aip.org
Similarly charged polymers in solution, known as polyelectrolytes, are known to form
aggregated structures in the presence of oppositely charged counterions. Understanding the …