Surface-assisted fabrication of low-dimensional carbon-based nanoarchitectures

D Han, J Zhu - Journal of Physics: Condensed Matter, 2021 - iopscience.iop.org
On-surface synthesis, as an alternative to traditional in-solution synthesis, has become an
emerging research field and attracted extensive attention over the past decade due to its …

On-Surface Synthesis of Antiaromatic and Open-Shell Indeno[2,1-b]fluorene Polymers and Their Lateral Fusion into Porous Ribbons

M Di Giovannantonio, K Eimre… - Journal of the …, 2019 - ACS Publications
Polycyclic hydrocarbons have received great attention due to their potential role in organic
electronics and, for open-shell systems with unpaired electron densities, in spintronics and …

Growth optimization and device integration of narrow‐bandgap graphene nanoribbons

G Borin Barin, Q Sun, M Di Giovannantonio, CZ Du… - Small, 2022 - Wiley Online Library
The electronic, optical, and magnetic properties of graphene nanoribbons (GNRs) can be
engineered by controlling their edge structure and width with atomic precision through …

Real-time imaging of on-surface Ullmann polymerization reveals an inhibiting effect of adatoms

D Dettmann, M Panighel… - Journal of the …, 2024 - ACS Publications
Ullmann coupling is a widely used reaction for the on-surface growth of low-dimensional
carbon nanomaterials. The irreversible nature of this reaction prevents the “self-healing” of …

On-Surface Synthesis of Multiple Cu Atom-Bridged Organometallic Oligomers

K Sun, K Sugawara, A Lyalin, Y Ishigaki, K Uosaki… - ACS …, 2023 - ACS Publications
A metal–metal bond between coordination complexes has the nature of a covalent bond in
hydrocarbons. While bimetallic and trimetallic compounds usually have three-dimensional …

On-surface Synthesis: What Happens Behind the Scenes?

S Stolz, M Di Giovannantonio, O Gröning, R Widmer - Chimia, 2022 - chimia.ch
On-surface synthesis has become a powerful approach to produce low-dimensional carbon-
based nanostructures with atomistic precision. A large variety of analytical tools and …

Theoretical Studies of the Mechanism of Ullmann Coupling of Naphthyl Halogen Derivatives to Binaphtyl on Coinage Metals

J Jung, D Mollenhauer - The Journal of Physical Chemistry C, 2023 - ACS Publications
In the field of on-surface synthesis, 2D molecular networks are formed by C–C coupling
reactions. The on-surface Ullmann coupling reaction results in the formation of a new C–C …

Identifying the convergent reaction path from predesigned assembled structures: Dissymmetrical dehalogenation of Br2Py on Ag(111)

J Hu, Z Liang, K Shen, L **e, H Zhang, C Huang… - Nano Research, 2021 - Springer
On-surface Ullmann coupling has been intensely utilized for the tailor-made fabrication of
conjugated frameworks towards molecular electronics, however, reaction mechanisms are …

Ullmann-Like Covalent Bond Coupling without Participation of Metal Atoms

T Zhang, R Li, X Hao, Q Zhang, H Yang, Y Hou… - ACS …, 2023 - ACS Publications
Ullmann-like on-surface synthesis is one of the most appropriate approaches for the bottom-
up fabrication of covalent organic nanostructures and many successes have been achieved …

Manifold dynamic non-covalent interactions for steering molecular assembly and cyclization

S Song, L Wang, J Su, Z Xu, CH Hsu, C Hua, P Lyu… - Chemical …, 2021 - pubs.rsc.org
Deciphering rich non-covalent interactions that govern many chemical and biological
processes is crucial for the design of drugs and controlling molecular assemblies and their …