A single-molecule blueprint for synthesis

I Stone, RL Starr, Y Zang, C Nuckolls… - Nature Reviews …, 2021 - nature.com
Chemical reactions that occur at nanostructured electrodes have garnered widespread
interest because of their potential applications in fields including nanotechnology, green …

Scanning probe microscopy in probing low-dimensional carbon-based nanostructures and nanomaterials

C Zhang, Z Yi, W Xu - Materials Futures, 2022 - iopscience.iop.org
Carbon, as an indispensable chemical element on Earth, has diverse covalent bonding
ability, which enables construction of extensive pivotal carbon-based structures in multiple …

Constructing covalent organic nanoarchitectures molecule by molecule via scanning probe manipulation

Q Zhong, A Ihle, S Ahles, HA Wegner, A Schirmeisen… - Nature Chemistry, 2021 - nature.com
Constructing low-dimensional covalent assemblies with tailored size and connectivity is
challenging yet often key for applications in molecular electronics where optical and …

Dramatic acceleration of the Hopf cyclization on gold (111): From enediynes to peri-fused diindenochrysene graphene nanoribbons

C Zhao, DD Bhagwandin, W Xu… - Journal of the …, 2024 - ACS Publications
Hopf et al. reported the high-temperature 6π-electrocyclization of cis-hexa-1, 3-diene-5-yne
to benzene in 1969. Subsequent studies using this cyclization have been limited by its very …

Chemical identification and bond control of π-skeletons in a coupling reaction

C Zhang, RB Jaculbia, Y Tanaka… - Journal of the …, 2021 - ACS Publications
Highly unsaturated π-rich carbon skeletons afford versatile tuning of structural and
optoelectronic properties of low-dimensional carbon nanostructures. However, methods …

Reassessing alkyne coupling reactions while studying the electronic properties of diverse pyrene linkages at surfaces

J Lawrence, MSG Mohammed, D Rey… - ACS …, 2021 - ACS Publications
The combination of alkyne and halogen functional groups in the same molecule allows for
the possibility of many different reactions when utilized in on-surface synthesis. Here, we …

Topological defects induced high-spin quartet state in truxene-based molecular graphenoids

C Li, Y Liu, Y Liu, FH Xue, D Guan, Y Li… - CCS …, 2023 - chinesechemsoc.org
Topological defects in graphene materials introduce exotic properties with both fundamental
importance and technological implications, absent in their defect-free counterparts. Although …

A Simple and Practical Bis-N-Heterocyclic Carbene as an Efficient Ligand in Cu-Catalyzed Glaser Reaction

J Liu, Y Zhu, J Luo, Z Zhu, L Zhao, X Zeng, D Li, J Chen… - Molecules, 2023 - mdpi.com
Conjugated diyne derivatives are important scaffolds in modern organic synthetic chemistry.
Using the Glaser reaction involves the coupling of terminal alkynes which can efficiently …

Open the door to the atomic world by single-molecule atomic force microscopy

S Fang, YH Hu - Matter, 2021 - cell.com
Single-molecule atomic force microscopy (sm-AFM) is a state-of-the-art AFM involving single-
molecule tip functionalization, characterization, and manipulation. The pioneering work of tip …

Modulating Copper Ladder Spacing in Copper Phenylacetylide for Enhanced Photocatalysis via Substituent Control

A Zhu, S Niu, N Zhao, Z Zhang… - ACS Applied Materials & …, 2024 - ACS Publications
Copper phenylacetylide (PACu) is a promising photocatalyst due to its unique copper ladder
(CL) electron transport channel, which facilitates efficient charge transfer. However, the …