Best‐practice DFT protocols for basic molecular computational chemistry

M Bursch, JM Mewes, A Hansen… - Angewandte Chemie …, 2022 - Wiley Online Library
Nowadays, many chemical investigations are supported by routine calculations of molecular
structures, reaction energies, barrier heights, and spectroscopic properties. The lion's share …

[HTML][HTML] Software for the frontiers of quantum chemistry: An overview of developments in the Q-Chem 5 package

E Epifanovsky, ATB Gilbert, X Feng, J Lee… - The Journal of …, 2021 - pubs.aip.org
This article summarizes technical advances contained in the fifth major release of the Q-
Chem quantum chemistry program package, covering developments since 2015. A …

Intermolecular interaction characteristics of the all-carboatomic ring, cyclo [18] carbon: Focusing on molecular adsorption and stacking

Z Liu, T Lu, Q Chen - Carbon, 2021 - Elsevier
Recently, an intriguing all-carboatomic ring, cyclo [18] carbon, was observed in the
condensed phase for the first time, and it quickly attracted widespread attention. In this …

DFT exchange: sharing perspectives on the workhorse of quantum chemistry and materials science

AM Teale, T Helgaker, A Savin, C Adamo… - Physical chemistry …, 2022 - pubs.rsc.org
In this paper, the history, present status, and future of density-functional theory (DFT) is
informally reviewed and discussed by 70 workers in the field, including molecular scientists …

A look at the density functional theory zoo with the advanced GMTKN55 database for general main group thermochemistry, kinetics and noncovalent interactions

L Goerigk, A Hansen, C Bauer, S Ehrlich… - Physical Chemistry …, 2017 - pubs.rsc.org
We present the GMTKN55 benchmark database for general main group thermochemistry,
kinetics and noncovalent interactions. Compared to its popular predecessor GMTKN30 …

Computational methods in heterogeneous catalysis

BWJ Chen, L Xu, M Mavrikakis - Chemical Reviews, 2020 - ACS Publications
The unprecedented ability of computations to probe atomic-level details of catalytic systems
holds immense promise for the fundamentals-based bottom-up design of novel …

CRYSTAL23: A program for computational solid state physics and chemistry

A Erba, JK Desmarais, S Casassa… - Journal of Chemical …, 2022 - ACS Publications
The Crystal program for quantum-mechanical simulations of materials has been bridging the
realm of molecular quantum chemistry to the realm of solid state physics for many years …

Approaching coupled cluster accuracy with a general-purpose neural network potential through transfer learning

JS Smith, BT Nebgen, R Zubatyuk, N Lubbers… - Nature …, 2019 - nature.com
Computational modeling of chemical and biological systems at atomic resolution is a crucial
tool in the chemist's toolset. The use of computer simulations requires a balance between …

Even more efficient quantum computations of chemistry through tensor hypercontraction

J Lee, DW Berry, C Gidney, WJ Huggins, JR McClean… - PRX Quantum, 2021 - APS
We describe quantum circuits with only O~(N) Toffoli complexity that block encode the
spectra of quantum chemistry Hamiltonians in a basis of N arbitrary (eg, molecular) orbitals …

Machine learning interatomic potentials and long-range physics

DM Anstine, O Isayev - The Journal of Physical Chemistry A, 2023 - ACS Publications
Advances in machine learned interatomic potentials (MLIPs), such as those using neural
networks, have resulted in short-range models that can infer interaction energies with near …