Highly oxygenated organic molecules (HOM) from gas-phase autoxidation involving peroxy radicals: A key contributor to atmospheric aerosol
Highly oxygenated organic molecules (HOM) are formed in the atmosphere via autoxidation
involving peroxy radicals arising from volatile organic compounds (VOC). HOM condense on …
involving peroxy radicals arising from volatile organic compounds (VOC). HOM condense on …
Global airborne sampling reveals a previously unobserved dimethyl sulfide oxidation mechanism in the marine atmosphere
Dimethyl sulfide (DMS), emitted from the oceans, is the most abundant biological source of
sulfur to the marine atmosphere. Atmospheric DMS is oxidized to condensable products that …
sulfur to the marine atmosphere. Atmospheric DMS is oxidized to condensable products that …
Atmospheric autoxidation is increasingly important in urban and suburban North America
Gas-phase autoxidation—regenerative peroxy radical formation following intramolecular
hydrogen shifts—is known to be important in the combustion of organic materials. The …
hydrogen shifts—is known to be important in the combustion of organic materials. The …
Particle-phase accretion forms dimer esters in pinene secondary organic aerosol
Secondary organic aerosol (SOA) is ubiquitous in the atmosphere and plays a pivotal role in
climate, air quality, and health. The production of low-volatility dimeric compounds through …
climate, air quality, and health. The production of low-volatility dimeric compounds through …
[HTML][HTML] H migration in peroxy radicals under atmospheric conditions
A large data set of rate coefficients for H migration in peroxy radicals is presented and
supplemented with literature data to derive a structure–activity relationship (SAR) for the title …
supplemented with literature data to derive a structure–activity relationship (SAR) for the title …
Chemistry of functionalized reactive organic intermediates in the earth's atmosphere: impact, challenges, and progress
The gas-phase oxidation of organic compounds is an important chemical process in the
Earth's atmosphere. It governs oxidant levels and controls the production of key secondary …
Earth's atmosphere. It governs oxidant levels and controls the production of key secondary …
Hydrotrioxide (ROOOH) formation in the atmosphere
Organic hydrotrioxides (ROOOH) are known to be strong oxidants used in organic synthesis.
Previously, it has been speculated that they are formed in the atmosphere through the gas …
Previously, it has been speculated that they are formed in the atmosphere through the gas …
Variable amine spacing determines depolymerization rate in polydiketoenamines
The design of circular polymers has emerged as a necessity due to the lack of efficient
recycling methods for many commodity plastics, particularly those used in durable products …
recycling methods for many commodity plastics, particularly those used in durable products …
Unimolecular reactions of peroxy radicals formed in the oxidation of α-pinene and β-pinene by hydroxyl radicals
Atmospheric oxidation of monoterpenes (emitted primarily by evergreen trees) is known to
contribute to the formation and growth of aerosol particles. While recent research has tied …
contribute to the formation and growth of aerosol particles. While recent research has tied …
New insights into the radical chemistry and product distribution in the OH-initiated oxidation of benzene
Emissions of aromatic compounds cause air pollution and detrimental health effects. Here,
we explore the reaction kinetics and products of key radicals in benzene photo-oxidation …
we explore the reaction kinetics and products of key radicals in benzene photo-oxidation …