Aerobic copper-catalyzed organic reactions

SE Allen, RR Walvoord, R Padilla-Salinas… - Chemical …, 2013 - ACS Publications
The chemistry of copper is extremely rich because it can easily access Cu0, CuI, CuII, and
CuIII oxidation states allowing it to act through one-electron or two-electron processes. As a …

Catalytic oxidation of alcohols: Recent advances

MN Kopylovich, APC Ribeiro, ECBA Alegria… - Advances in …, 2015 - Elsevier
This review concerns metal-catalyzed reactions of oxidation of alcohols to the respective
products, mainly ketones and aldehydes, mostly within the period of 2010–2014. Both …

Synthesis, characterization, DNA binding, and biological action of dimedone arylhydrazone chelates

MA El‐Bindary, AA El‐Bindary - Applied Organometallic …, 2022 - Wiley Online Library
A chain of metal (II) chelates that M= Co2+, Ni2+, and Cu2+ have been produced from 2‐(4‐
sulfadiazine) hydrazono dimedone (HL) and characterized on analyses of elemental …

Synthesis, spectral characterization, DNA binding, catalytic and in vitro cytotoxicity of some metal complexes

HA Kiwaan, AS El-Mowafy, AA El-Bindary - Journal of Molecular Liquids, 2021 - Elsevier
Abstract A series of 2-(4-sulfamethazine) hydrazono-5, 5-dimethylcyclohexane-1, 3-dione
(HL) and its complexes of Co (II), Ni (II) and Cu (II)(1–3) were synthesized. Elemental …

Synthesis, characterization, DFT calculation, DNA binding and antimicrobial activities of metal complexes of dimedone arylhydrazone

KS Abou-Melha, GA Al-Hazmi, I Althagafi… - Journal of Molecular …, 2021 - Elsevier
The diazotization, coupling and metallization process was employed to create hydrazone
chelating ligand (HL) and its Co (II), Cu (II) and Ni (II) complexes. Elemental analysis, FT-IR …

Resonance‐assisted hydrogen bonding as a driving force in synthesis and a synthon in the design of materials

KT Mahmudov, AJL Pombeiro - Chemistry–A European …, 2016 - Wiley Online Library
Resonance‐assisted hydrogen bonding (RAHB), a concept introduced by Gilli and co‐
workers in 1989, concerns a kind of intramolecular H‐bonding strengthened by a …

Multicopper complexes and coordination polymers for mild oxidative functionalization of alkanes

AM Kirillov, MV Kirillova, AJL Pombeiro - Coordination Chemistry Reviews, 2012 - Elsevier
Alkanes (main components of natural gas and oil) are rather inert compounds and their
functionalization under mild conditions, toward the synthesis of added value organic …

C–H functionalization: thoroughly tuning ligands at a metal ion, a chemist can greatly enhance catalyst's activity and selectivity

GB Shul'pin - Dalton Transactions, 2013 - pubs.rsc.org
This brief essay consists of a few “exciting stories” devoted to relations within a metal-
complex catalyst between a metal ion and a coordinated ligand. When, as in the case of a …

Homogeneous oxidative transformations mediated by copper catalyst systems

L Marais, HCM Vosloo, AJ Swarts - Coordination Chemistry Reviews, 2021 - Elsevier
Oxidative transformations involve the conversion of organic substrates, through various
processes to obtain oxygenates such as alcohols, phenolic and carbonyl compounds which …

Synthesis, characterization, DNA binding and antitumor activities of Cu (II) complexes

AF Shoair, AA El-Bindary, NA El-Ghamaz… - Journal of Molecular …, 2018 - Elsevier
A series of Cu (II) complexes of 5, 5-dimethyl-2-(2-arylhydrazono) cyclohexane-1, 3-dione
(HL n) were synthesized by the coupling of dimedone with aniline and its derivatives. These …