Defect-enabling zirconium-based metal–organic frameworks for energy and environmental remediation applications

S Daliran, AR Oveisi, CW Kung, U Sen… - Chemical Society …, 2024 - pubs.rsc.org
This comprehensive review explores the diverse applications of defective zirconium-based
metal–organic frameworks (Zr-MOFs) in energy and environmental remediation. Zr-MOFs …

Power of infrared and Raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules

KI Hadjiivanov, DA Panayotov, MY Mihaylov… - Chemical …, 2020 - ACS Publications
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

Highly defective ultra-small tetravalent MOF nanocrystals

S Dai, C Simms, G Patriarche, M Daturi, A Tissot… - Nature …, 2024 - nature.com
The size and defects in crystalline inorganic materials are of importance in many
applications, particularly catalysis, as it often results in enhanced/emerging properties. So …

New trends in nanoarchitectured SERS substrates: nanospaces, 2D materials, and organic heterostructures

O Guselnikova, H Lim, HJ Kim, SH Kim, A Gorbunova… - Small, 2022 - Wiley Online Library
This article reviews recent fabrication methods for surface‐enhanced Raman spectroscopy
(SERS) substrates with a focus on advanced nanoarchitecture based on noble metals with …

MOFs with bridging or terminal hydroxo ligands: Applications in adsorption, catalysis, and functionalization

I Ahmed, MMH Mondol, MJ Jung, GH Lee… - Coordination Chemistry …, 2023 - Elsevier
Metal-organic frameworks (MOFs) are popular porous materials prepared from metallic
species and organic linkers via the formation of coordination bonds. The applications and …

Generating catalytic sites in UiO-66 through defect engineering

X Feng, HS Jena, C Krishnaraj, K Leus… - … Applied Materials & …, 2021 - ACS Publications
UiO-66 is regarded as an epitome of metal–organic frameworks (MOFs) because of its
stability. Defect engineering has been used as a toolbox to alter the performance of MOFs …

Switching on the photocatalysis of metal–organic frameworks by engineering structural defects

X Ma, L Wang, Q Zhang… - Angewandte Chemie …, 2019 - Wiley Online Library
Defect engineering is a versatile approach to modulate band and electronic structures as
well as materials performance. Herein, metal–organic frameworks (MOFs) featuring …

Electronic structure modeling of metal–organic frameworks

JL Mancuso, AM Mroz, KN Le, CH Hendon - Chemical reviews, 2020 - ACS Publications
Owing to their molecular building blocks, yet highly crystalline nature, metal–organic
frameworks (MOFs) sit at the interface between molecule and material. Their diverse …

Boosting photocatalytic hydrogen peroxide production from oxygen and water using a hafnium-based metal–organic framework with missing-linker defects and nickel …

Y Kondo, K Honda, Y Kuwahara, K Mori… - ACS …, 2022 - ACS Publications
Metal–organic frameworks (MOFs) are one of the most promising candidates for
photocatalytic hydrogen peroxide (H2O2) production from dioxygen (O2) and water …

Unveiling and understanding the remarkable enhancement in the catalytic activity by the defect creation in UIO-66 during the catalytic transfer hydrodeoxygenation of …

AK Kar, R Sarkar, AK Manal, R Kumar… - Applied Catalysis B …, 2023 - Elsevier
The catalytic transfer hydrodeoxygenation of vanillin is generally achieved using noble
metal-based catalysts. Herein, we report a mechanistic investigation of the catalytic transfer …