Green chemistry in the synthesis of pharmaceuticals
The principles of green chemistry (GC) can be comprehensively implemented in green
synthesis of pharmaceuticals by choosing no solvents or green solvents (preferably water) …
synthesis of pharmaceuticals by choosing no solvents or green solvents (preferably water) …
The broadening reach of frustrated Lewis pair chemistry
BACKGROUND Since the work of Sabatier 100 year ago, chemists have turned almost
exclusively to metals to activate H2 by weakening or cleaving its central bond. This …
exclusively to metals to activate H2 by weakening or cleaving its central bond. This …
Frustrated Lewis pair chemistry: development and perspectives
Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …
solution that are deterred from strong adduct formation by steric and/or electronic factors …
FLP catalysis: main group hydrogenations of organic unsaturated substrates
J Lam, KM Szkop, E Mosaferi… - Chemical Society Reviews, 2019 - pubs.rsc.org
This article is focused on recent developments in main group mediated hydrogenation
chemistry and catalysis using “frustrated Lewis pairs”(FLPs). The broading range of …
chemistry and catalysis using “frustrated Lewis pairs”(FLPs). The broading range of …
Frustrated lewis pairs
The articulation of the notion of “frustrated Lewis pairs”(FLPs), which emerged from the
discovery that H2 can be reversibly activated by combinations of sterically encumbered …
discovery that H2 can be reversibly activated by combinations of sterically encumbered …
Thermodynamic hydricity of transition metal hydrides
Transition metal hydrides play a critical role in stoichiometric and catalytic transformations.
Knowledge of free energies for cleaving metal hydride bonds enables the prediction of …
Knowledge of free energies for cleaving metal hydride bonds enables the prediction of …
Frustrated Lewis pairs: from concept to catalysis
Conspectus Frustrated Lewis pair (FLP) chemistry has emerged in the past decade as a
strategy that enables main-group compounds to activate small molecules. This concept is …
strategy that enables main-group compounds to activate small molecules. This concept is …
Metallomimetic chemistry of boron
The study of main-group molecules that behave and react similarly to transition-metal (TM)
complexes has attracted significant interest in recent decades. Most notably, the attractive …
complexes has attracted significant interest in recent decades. Most notably, the attractive …
A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes
The bond activation chemistry of B (C6F5) 3 and related electron-deficient boranes is
currently experiencing a renaissance due to the fascinating development of frustrated Lewis …
currently experiencing a renaissance due to the fascinating development of frustrated Lewis …
Frustrated Lewis pair chemistry of CO
Transition metal species readily capture and react with CO as the metal can act both as an
acceptor and donor of electron density. In contrast, such a situation is less common in the …
acceptor and donor of electron density. In contrast, such a situation is less common in the …