Machine learning the quantum-chemical properties of metal–organic frameworks for accelerated materials discovery

AS Rosen, SM Iyer, D Ray, Z Yao, A Aspuru-Guzik… - Matter, 2021 - cell.com
The modular nature of metal–organic frameworks (MOFs) enables synthetic control over
their physical and chemical properties, but it can be difficult to know which MOFs would be …

Computational catalysis for metal-organic frameworks: an overview

GA McCarver, T Rajeshkumar, KD Vogiatzis - Coordination Chemistry …, 2021 - Elsevier
Abstract Metal-organic frameworks (MOFs), a family of porous hybrid organic/inorganic
materials, have shown great promise for many challenging chemical applications including …

Single–atom catalysts based on Fenton-like/peroxymonosulfate system for water purification: design and synthesis principle, performance regulation and catalytic …

L Hao, C Guo, Z Hu, R Guo, X Liu, C Liu, Y Tian - Nanoscale, 2022 - pubs.rsc.org
Novel single-atom catalysts (SACs) have become the frontier materials in the field of
environmental remediation, especially wastewater purification because of their nearly 100 …

Nano-porous bimetallic CuCo-MOF-74 with coordinatively unsaturated metal sites for peroxymonosulfate activation to eliminate organic pollutants: Performance and …

H Li, Z Yang, S Lu, L Su, C Wang, J Huang, J Zhou… - Chemosphere, 2021 - Elsevier
The importance of clean water resources for maintaining sustainable development of society
is self-evident. In this study, bimetallic metal-organic framework (CuCo-MOF-74) was …

New strategies for direct methane-to-methanol conversion from active learning exploration of 16 million catalysts

A Nandy, C Duan, C Goffinet, HJ Kulik - Jacs Au, 2022 - ACS Publications
Despite decades of effort, no earth-abundant homogeneous catalysts have been discovered
that can selectively oxidize methane to methanol. We exploit active learning to …

High Gravimetric and Volumetric Ammonia Capacities in Robust Metal–Organic Frameworks Prepared via Double Postsynthetic Modification

DW Kim, DW Kang, M Kang, DS Choi… - Journal of the …, 2022 - ACS Publications
Ammonia is a promising energy vector that can store the high energy density of hydrogen.
For this reason, numerous adsorbents have been investigated as ammonia storage …

Surface-functionalized PVDF membranes by facile synthetic Cu-MOF-74 for enhanced contaminant degradation and antifouling performance

H Zheng, Y Zhou, D Wang, M Zhu, X Sun… - Colloids and Surfaces A …, 2022 - Elsevier
Catalytic membrane reactors (CMR) based on the sulfate-based advanced oxidation
processes (SR-AOPs) have exhibited fantastic applications prospects in water treatment. We …

Influence of first and second coordination environment on structural Fe (II) sites in MIL-101 for C–H bond activation in methane

JG Vitillo, CC Lu, CJ Cramer, A Bhan, L Gagliardi - ACS Catalysis, 2020 - ACS Publications
Divalent iron sites in tri-iron oxo-centered metal nodes in metal–organic frameworks (MOFs)
catalyze light alkane oxidation. The first two steps of the reaction sequence, which are also …

Gas adsorption and framework flexibility of CALF-20 explored via experiments and simulations

R Oktavian, R Goeminne, LT Glasby, P Song… - Nature …, 2024 - nature.com
In 2021, Svante, in collaboration with BASF, reported successful scale up of CALF-20
production, a stable MOF with high capacity for post-combustion CO2 capture which exhibits …

Correlating structure-activity-stability relationship of high-valent 3d-metal-based MOFs and MOF-derived materials for electrochemical energy conversion and storage

B Singh, R Kumar, A Draksharapu - Coordination Chemistry Reviews, 2025 - Elsevier
The energy crises and environmental pollution are the current main challenges for society.
In this regard, efficient electrochemical energy conversion and storage technologies could …