Conspectus Comprising periodically repeating inorganic nodes and organic linkers, metal–
organic frameworks (MOFs) represent a novel class of porous molecular solids with well …

Developments in the confinement of phosphines within micro-or nano-environments are
explored. Phosphines are ubiquitous across metal coordination chemistry and underpin …

Post‐synthetic modification of the hafnium metal–organic framework MOF‐808 (Hf) to
include triarylphosphine ligands is reported. Sulfonated phenylphosphines are incorporated …

Two zirconium–organic frameworks were synthesized by exchanging the acetate ligands in
[Zr12O8 (OH) 8 (CH3COO) 24] with polydentate linkers. Partial substitution of acetate groups …

Abstract A new 2D Cu (II)-based metal-organic framework,[(Cu 2 BPDSDC· 4DMF)· 2DMF] n
(namely 1), was constructed by a linker biphenyl-3, 3′-disulfonyl-4, 4′-dicarboxylic acid (H …

A Co (II)-based MOF,{[Co3 (L) 2 (bpb)(DMA)(H2O)]· Solvents} n (RH-1), with a unique
interpenetrated framework has been solvothermally prepared. Because of its unsaturated …

Postsynthetic phospha-Mannich condensation has been investigated for the design of solid-
state phosphine ligands using amine-functionalized metal–organic frameworks (MOFs) …

Two covalent organic frameworks comprising Lewis basic PIII centers and Lewis acidic
boron atoms were prepared by poly‐condensation reactions of newly obtained tris (4 …

The metal–organic framework [Y (tbpp)]· n DMF (1) was synthesized from yttrium (III) nitrate
and the tritopic linker tris (4′-carboxy [1, 1′-biphenyl]-4-yl) phosphine (H3tbpp). The …

Three new coordination polymers [Co (L)(1, 2, 4, 5-BTC) 0.5 (H 2 O)] n (1),{[Ni (L)(1, 2-
BDC)(H 2 O) 3]· H 2 O} n (2) and {[Zn 3 (L) 2 (1, 3, 5-BTC) 2 (H 2 O) 2]· 3H 2 O} n (3)[L= 3, 6 …