Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …

The main contributions in the field of first-row transition-metal-catalyzed (base-metal-
catalyzed) carbonylative transformations have been summarized and discussed. The …

As two coexisting and fast-growing research fields in modern synthetic chemistry, the
merging of organocatalysis and C–H bond functionalization is well foreseeable, and the joint …

Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Effective methodology to functionalize C–H bonds requires overcoming the key challenge of
differentiating among the multitude of C–H bonds that are present in complex organic …

The development of methods for the direct conversion of carbonshydrogen bonds into
carbon-oxygen, carbon-halogen, carbon-nitrogen, carbon-sulfur, and carbon-carbon bonds …

Chiral cyclopentadienyl rhodium (CpRh) complex‐catalyzed asymmetric C− H
functionalization reactions have witnessed a significant progress in organic synthesis. In …

A Rh-catalyzed intermolecular coupling of diazomalonates with arene C–H bonds is
reported. The reaction is initiated by electrophilic C–H activation, which is followed by …

The abundance of the biaryl structural motif in natural products, in biologically active
molecules and in materials chemistry has positioned aryl–aryl (Ar–Ar) bond formation high …

Transition metal catalyzed carbonylation reactions using carbon monoxide as the C-1
source have occupied an all important position in catalysis which is subsequently related to …