Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers
P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
Modelling approaches for chiral chromatography on polysaccharide-based and macrocyclic antibiotic chiral selectors: A review
P De Gauquier, K Vanommeslaeghe… - Analytica Chimica …, 2022 - Elsevier
An overview of molecular modelling approaches, related to chiral separations on
polysaccharide-based and macrocyclic antibiotic chiral selectors, is presented. Both …
polysaccharide-based and macrocyclic antibiotic chiral selectors, is presented. Both …
Stereoselective processes based on σ-hole interactions
The σ-hole interaction represents a noncovalent interaction between atoms with σ-hole (s)
on their surface (such as halogens and chalcogens) and negative sites. Over the last …
on their surface (such as halogens and chalcogens) and negative sites. Over the last …
Halogen bond in separation science: A critical analysis across experimental and theoretical results
The halogen bond (XB) is a noncovalent interaction involving a halogen acting as
electrophile and a Lewis base. In the last decades XB has found practical application in …
electrophile and a Lewis base. In the last decades XB has found practical application in …
Recent studies of docking and molecular dynamics simulation for liquid‐phase enantioseparations
Liquid‐phase enantioseparations have been fruitfully applied in several fields of science.
Various applications along with technical and theoretical advancements contributed to …
Various applications along with technical and theoretical advancements contributed to …
[HTML][HTML] Enantioselective separation of racemates using CHIRALPAK IG amylose-based chiral stationary phase under normal standard, non-standard and reversed …
A Ghanem, C Wang - Journal of Chromatography A, 2018 - Elsevier
We have previously reported on the solvent versatility of immobilized amylose and cellulose-
based chiral stationary phases in enantioselective liquid chromatographic separation of …
based chiral stationary phases in enantioselective liquid chromatographic separation of …
Chiral chalcogen bond donors based on the 4, 4′-bipyridine scaffold
Organocatalysis through chalcogen bonding (ChB) is in its infancy, as its proof-of-principle
was only reported in 2016. Herein, we report the design and synthesis of new chiral ChB …
was only reported in 2016. Herein, we report the design and synthesis of new chiral ChB …
Unravelling functions of halogen substituents in the enantioseparation of halogenated planar chiral ferrocenes on polysaccharide-based chiral stationary phases …
Planar chiral halogenated ferrocenes have come in useful as synthetic intermediates over
the years, allowing for the preparation of functionalized derivatives for catalysis, material …
the years, allowing for the preparation of functionalized derivatives for catalysis, material …
Efficient Pincer‐Ruthenium Catalysts for Kharasch Addition of Carbon Tetrachloride to Styrene
A series of NNN pincer‐ruthenium complexes (R2NNN) RuCl2 (PPh3)(R= Cyclohexyl (Cy), t‐
butyl (tBu), i‐propyl (iPr) and phenyl (Ph)) have been synthesized and characterized. These …
butyl (tBu), i‐propyl (iPr) and phenyl (Ph)) have been synthesized and characterized. These …
Recognition mechanisms of chiral selectors: An overview
GKE Scriba - Chiral Separations: Methods and Protocols, 2019 - Springer
Stereospecific recognition of chiral molecules plays an important role in nature as the basis
of the interaction of chiral bioactive compounds with the chiral target structures. In separation …
of the interaction of chiral bioactive compounds with the chiral target structures. In separation …