Gold-catalyzed reactions of specially activated alkynes, allenes, and alkenes

D Campeau, DF León Rayo, A Mansour… - Chemical …, 2020 - ACS Publications
This review describes the gold-catalyzed reactions of specially activated alkynes, allenes,
and alkenes. Such species are characterized by the presence of either electron-donating or …

Gold-catalyzed nucleophilic cyclization of functionalized allenes: a powerful access to carbo-and heterocycles

N Krause, C Winter - Chemical reviews, 2011 - ACS Publications
Allenes are highly valuable synthetic precursors in preparative organic chemistry because of
their ability to undergo a variety of transformations. 1 Among many different reaction modes …

Gold-catalyzed organic reactions

ASK Hashmi - Chemical reviews, 2007 - ACS Publications
Gold has accompanied mankind from the very early days; no name of a chemist is
associated with the discovery of the element gold. It is probably the only chemical element …

Catalytic carbophilic activation: catalysis by platinum and gold π acids

A Fürstner, PW Davies - Angewandte Chemie International …, 2007 - Wiley Online Library
The ability of platinum and gold catalysts to effect powerful atom‐economic transformations
has led to a marked increase in their utilization. The quite remarkable correlation of their …

Alternative synthetic methods through new developments in catalysis by gold

A Arcadi - Chemical Reviews, 2008 - ACS Publications
Synthetic chemists are constantly challenged to consider more environmentally benign
methods for generation of the desired target molecules. 1 Recently, there has been an …

Coinage metal-assisted synthesis of heterocycles

NT Patil, Y Yamamoto - Chemical reviews, 2008 - ACS Publications
Substituted heterocycles are a structural component of a vast number of biologically active
natural and non-natural compounds. Synthesis of various heterocycles has been a research …

Allenamides: a powerful and versatile building block in organic synthesis

T Lu, Z Lu, ZX Ma, Y Zhang, RP Hsung - Chemical reviews, 2013 - ACS Publications
In the past four decades, allenes have progressively risen from an unenviable status of
being a structural curiosity to becoming one of the most powerful and versatile synthetic …

Silver-mediated synthesis of heterocycles

M Alvarez-Corral, M Munoz-Dorado… - Chemical …, 2008 - ACS Publications
Heterocyclic synthesis involving transition metal complexes has become of common use in
the past decade because a transition-metal-catalyzed reaction can directly build …

[PDF][PDF] Recent advances in asymmetric gold catalysis

S Sengupta, X Shi - ChemCatChem, 2010 - academia.edu
However, despite its high efficiency in alkyne and allene activation, gold catalysts, like many
other transition metal complexes, inherit some limitations that prevent them from being …

Recent advances in syntheses of heterocycles and carbocycles via homogeneous gold catalysis. Part 1: Heteroatom addition and hydroarylation reactions of alkynes …

HC Shen - Tetrahedron, 2008 - Elsevier
Despite the extensive use of gold and gold salts in heterogeneous catalysis since the 1960s,
1 the golden era of homogeneous gold catalysis has begun at the end of the 20th century …