Confinement of luminescent guests in metal–organic frameworks: understanding pathways from synthesis and multimodal characterization to potential applications of …

M Gutiérrez, Y Zhang, JC Tan - Chemical Reviews, 2022 - ACS Publications
This review gives an authoritative, critical, and accessible overview of an emergent class of
fluorescent materials termed “LG@ MOF”, engineered from the nanoscale confinement of …

Electron-volt neutron spectroscopy: beyond fundamental systems

C Andreani, M Krzystyniak, G Romanelli… - Advances in …, 2017 - Taylor & Francis
This work provides an up-to-date account of the use of electron-volt neutron spectroscopy in
materials research. This is a growing area of neutron science, capitalising upon the unique …

Host–guest intercalation chemistry in MXenes and its implications for practical applications

H Chen, H Ma, C Li - ACS nano, 2021 - ACS Publications
The ever-increasing demand on develo** layered materials for practical applications,
such as electrochemical energy storage, responsive materials, nanofluidics, and …

Identifying the role of terahertz vibrations in metal-organic frameworks: from gate-opening phenomenon to shear-driven structural destabilization

MR Ryder, B Civalleri, TD Bennett, S Henke, S Rudić… - Physical review …, 2014 - APS
We present an unambiguous identification of low-frequency terahertz vibrations in the
archetypal imidazole-based metal-organic framework (MOF) materials: ZIF-4, ZIF-7, and ZIF …

Detecting molecular rotational dynamics complementing the low-frequency terahertz vibrations in a zirconium-based metal-organic framework

MR Ryder, B Van de Voorde, B Civalleri, TD Bennett… - Physical Review Letters, 2017 - APS
We show clear experimental evidence of cooperative terahertz (THz) dynamics observed
below 3 THz (∼ 100 cm− 1), for a low-symmetry Zr-based metal-organic framework …

Green reconstruction of MIL-100 (Fe) in water for high crystallinity and enhanced guest encapsulation

BE Souza, AF Möslein, K Titov, JD Taylor… - ACS Sustainable …, 2020 - ACS Publications
MIL-100 (Fe) is a highly porous metal–organic framework (MOF), considered as a promising
carrier for drug delivery and for gas separation and capture applications. However, this …

Probing atomic-scale symmetry breaking by rotationally invariant machine learning of multidimensional electron scattering

MP Oxley, M Ziatdinov, O Dyck, AR Lupini… - npj Computational …, 2021 - nature.com
The 4D scanning transmission electron microscopy (STEM) method maps the structure and
functionality of solids on the atomic scale, yielding information-rich data sets describing the …

Neutron instruments for research in coordination chemistry

ZL Xue, AJ Ramirez‐Cuesta, CM Brown… - European Journal of …, 2019 - Wiley Online Library
Neutron diffraction and spectroscopy offer unique insight into structures and properties of
solids and molecular materials. All neutron instruments located at the various neutron …

Thermal neutron cross sections of amino acids from average contributions of functional groups

G Romanelli, D Onorati, P Ulpiani… - Journal of Physics …, 2021 - iopscience.iop.org
The experimental thermal neutron cross sections of the 20 proteinogenic amino acids have
been measured over the incident-neutron energy range spanning from 1 meV to 10 keV and …

Neutrons for cultural heritage—techniques, sensors, and detection

G Festa, G Romanelli, R Senesi, L Arcidiacono… - Sensors, 2020 - mdpi.com
Advances in research in Cultural Heritage see increasing application of a multidisciplinary
approach and the combined use of physical and chemical characterization of artefacts that …